Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 365, Issue 3, Pages 381-387Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.202201199
Keywords
Cycloaddition; Indene-2-carbaldehydes; 4-Vinylbenzoxazinanones; Regioselectivity; Enantioselectivity
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Palladium-catalyzed asymmetric [4+3] cycloadditions of indene-2-carbaldehydes and 4-vinyl benzoxazinanones proceeded smoothly in the presence of chiral phosphine ligands to give the corresponding functionalized 5H-benzo[b]azepines (26 examples, 60% to 89% yield, 88:12 to 95.5:4.5 er) under mild conditions.
Palladium-catalyzed asymmetric [4+3] cycloadditions of indene-2-carbaldehydes and 4-vinyl benzoxazinanones proceeded smoothly in the presence of chiral phosphine ligands to give the corresponding functionalized 5H-benzo[b]azepines (26 examples, 60% to 89% yield, 88:12 to 95.5:4.5 er) under mild conditions.
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