Solution-Processed Pure Red TADF Organic Light-Emitting Diodes With High External Quantum Efficiency and Saturated Red Emission Color

In spite of recent research progress in red thermally activated delayed fluorescence (TADF) emitters, highly efficient solution-processable pure red TADF emitters are rarely reported. Most of the red TADF emitters reported to date are designed using a rigid acceptor unit which renders them insoluble and unsuitable for solution-processed organic light-emitting diodes (OLEDs). To resolve this issue, a novel TADF emitter, 6,7-bis(4-(bis(4-(tert-butyl)phenyl)amino)phenyl)-2,3-bis(4-(tert-butyl)phenyl)quinoxaline-5,8-dicarbonitrile (tBuTPA-CNQx) is designed and synthesized. The highly twisted donor-acceptor architecture and appropriate highest occupied molecular orbital/lowest unoccupied molecular orbital distribution lead to a very small singlet-triplet energy gap of 0.07 eV, high photoluminescence quantum yield of 92%, and short delayed fluorescence lifetime of 52.4 mu s. The peripheral t-butyl phenyl decorated quinoxaline acceptor unit and t-butyl protected triphenylamine donor unit are proven to be useful building blocks to improve solubility and minimize the intermolecular interaction. The solution-processed OLED based on tBuTPA-CNQx achieves a high external quantum efficiency (EQE) of 16.7% with a pure red emission peak at 662 nm, which is one of the highest EQE values reported till date in the solution-processed pure red TADF OLEDs. Additionally, vacuum-processable OLED based on tBuTPA-CNQx exhibits a high EQE of 22.2% and negligible efficiency roll-off.

Automated summary

Despite recent progress, highly efficient solution-processable pure red thermally activated delayed fluorescence (TADF) emitters are rare. To address this issue, a novel TADF emitter, tBuTPA-CNQx, was designed and synthesized, which exhibited a small singlet-triplet energy gap, high photoluminescence quantum yield, and short delayed fluorescence lifetime. The use of specific building blocks improved solubility and minimized intermolecular interaction. The resulting OLED achieved high external quantum efficiency and pure red emission peak, making it one of the highest performing pure red TADF OLEDs reported to date.