Journal
ADVANCED FUNCTIONAL MATERIALS
Volume 33, Issue 4, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.202209726
Keywords
Co-N-4; nitrogen-doped graphene; oxygen reduction reaction; single atom catalyst; Zn-air battery
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In this study, a self-sacrificing template strategy was developed to fabricate high metal loading cobalt single atoms and atomic clusters on nitrogen-doped graphene. The resulting catalyst exhibited enhanced electrocatalytic activity for oxygen reduction reaction, outperforming Pt/C catalysts. It also showed excellent performance in zinc-air batteries, indicating great potential for energy storage applications.
The development of precious-metal alternative electrocatalysts for oxygen reduction reaction (ORR) is highly desired for a variety of fuel cells, and single atom catalysts (SACs) have been envisaged to be the promising choice. However, there remains challenges in the synthesis of high metal loading SACs (>5 wt.%), thus limiting their electrocatalytic performance. Herein, a facile self-sacrificing template strategy is developed for fabricating Co single atoms along with Co atomic clusters co-anchored on porous-rich nitrogen-doped graphene (Co SAs/AC@NG), which is implemented by the pyrolysis of dicyandiamide with the formation of layered g-C3N4 as sacrificed templates, providing rich anchoring sites to achieve high Co loading up to 14.0 wt.% in Co SAs/AC@NG. Experiments combined with density functional theory calculations reveal that the co-existence of Co single atoms and clusters with underlying nitrogen doped carbon in the optimized Co40SAs/AC@NG synergistically contributes to the enhanced electrocatalysis for ORR, which outperforms the state-of-the-art Pt/C catalysts with presenting a high half-wave potential (E-1/2 = 0.890 V) and robust long-term stability. Moreover, the Co40SAs/AC@NG presents excellent performance in Zn-air battery with a high-peak power density (221 mW cm(-2)) and strong cycling stability, demonstrating great potential for energy storage applications.
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