☆ 4.8 Article

An Elastic Cross-Linked Binder for Silicon Anodes in Lithium-Ion Batteries with a High Mass Loading

ACS APPLIED MATERIALS & INTERFACES (2023)

Related references

Note: Only part of the references are listed.

Article Chemistry, Multidisciplinary

Micrometer-Sized SiMgyOx with Stable Internal Structure Evolution for High-Performance Li-Ion Battery Anodes

Yi-Fan Tian et al.

Summary: This work addresses the challenge of volume variation in micrometer-sized Si-based anode materials during electrochemical processes by preparing in situ magnesium-doped SiOx microparticles. The resulting anode exhibits high reversible capacities, stable cycling performance, and low electrode expansion. A cylindrical-type cell based on this anode demonstrates a 1000-cycle operation life, meeting practical storage requirements for consumer electronics and electric vehicles.

ADVANCED MATERIALS (2022)

Add to Collection

Review Chemistry, Multidisciplinary

Key Factors for Binders to Enhance the Electrochemical Performance of Silicon Anodes through Molecular Design

Haoli Wang et al.

Summary: Silicon is considered a promising anode material for lithium-ion batteries due to its high theoretical capacity, but its application is limited by vast volume change and low electrical conductivity. In the silicon anode system, binders play a crucial role in mechanical performance and conductive integrity. This review summarizes key factors affecting binders' performance and provides commonly used modification methods to improve binder performance.

SMALL (2022)

Add to Collection

Article Chemistry, Physical

Recent progress and future perspective on practical silicon anode-based lithium ion batteries

Lin Sun et al.

Summary: This article provides a brief overview of the development history of silicon anode lithium-ion batteries and highlights the challenges and countermeasures in practical applications. Solutions are proposed for structure regulation, interface modulation, and novel binder and electrolyte design, with a focus on future research on full cell performances and all solid-state batteries.

ENERGY STORAGE MATERIALS (2022)

Add to Collection

Article Chemistry, Physical

Blood clot-inspired viscoelastic fibrin gel: New aqueous binder for silicon anodes in lithium ion batteries

Woong-Ju Kim et al.

Summary: This study introduces a new binder based on fibrin for silicon anodes in lithium-ion batteries. The binder, with abundant polar functional groups and time-dependent viscoelastic behavior, shows better cycling stability and rate performance than other binders. Further optimization by mixing with other binders and ionic cross-linking results in an advanced binder with remarkable cycling stability.

ENERGY STORAGE MATERIALS (2022)

Add to Collection

Article Nanoscience & Nanotechnology

Scalable and low-cost synthesis of porous silicon nanoparticles as high-performance lithium-ion battery anode

Z. Yan et al.

Summary: We designed porous silicon nanoparticles with nanosize and porous structures using a simple alkaline etching method. Coated with a carbon layer, these porous nanoparticles exhibited excellent discharge capacity, capacity retention, and rate capacity, which can be attributed to their ability to accommodate the volume changes of the silicon anode.

MATERIALS TODAY NANO (2022)

Add to Collection

Article Chemistry, Physical

Understanding the Role of Polymer Interactions within Binders in Composite Lithium-Ion Anodes

Miguel A. Gonzalez et al.

Summary: The study investigates the impact of intercomponent interactions between polymers in a co-binder polymeric system on electrochemical performance. By altering the chain length of the polymers, different polymer configurational regimes are discovered, contributing to the development of high-performing power-dense anode binder systems.

JOURNAL OF PHYSICAL CHEMISTRY C (2022)

Add to Collection

Article Nanoscience & Nanotechnology

Lithium/Boron Co-doped Micrometer SiOx as Promising Anode Materials for High-Energy-Density Li-Ion Batteries

Xiao-Dong Li et al.

Summary: In this study, a Li/B co-doping strategy was developed to enhance the initial Coulombic efficiency and cycling stability of SiOx@C anodes, while alleviating volume expansion and pulverization. The findings are significant for the practical application of high-energy-density lithium-ion batteries.

ACS APPLIED MATERIALS & INTERFACES (2022)

Add to Collection

Article Electrochemistry

A dual force cross-linked γ-PGA-PAA binder enhancing the cycle stability of silicon-based anodes for lithium-ion batteries

Ming-Jia Guo et al.

Summary: In this study, a natural polymer cross-linked binder, derived from poly-glutamic acid and poly-acrylic acid, was synthesized and applied to improve the cycling performance of Silicon (Si) anode materials. The cross-linked binder showed excellent adhesion to Si particles and enhanced the capacity retention and structural integrity of Si and SiO electrodes.

ELECTROCHIMICA ACTA (2022)

Add to Collection

Article Green & Sustainable Science & Technology

Cross-linked binder enables reversible volume changes of Si-based anodes from sustainable photovoltaic waste silicon

S. Zhang et al.

Summary: In this study, a novel three-dimensional cross-linked binder was constructed by forming hydrogen bonds between carboxymethyl cellulose (CMC) and ethylenediaminetetraacetic acid disodium (EDTA-2Na), with EDTA-2Na further coordinated to calcium ions (Ca2+). The cross-linked CMC/EDTA-Ca2+ binder exhibited improved mechanical properties and higher adhesion strength compared to the bare CMC binder, enabling reversible volume change and enhancing the cycling performance of Si/C anode. Moreover, the low-cost and abundant photovoltaic waste silicon was recycled as a Si source for fabricating the Si/C anode.

MATERIALS TODAY SUSTAINABILITY (2022)

Add to Collection

Article Chemistry, Multidisciplinary

A highly stable pre-lithiated SiOx anode coated with a salt-in-polymer layer

He Tian et al.

Summary: In this study, an artificial salt-in-polymer solid electrolyte interface (SEI) was constructed by decomposing Li salts to form poly-(1,3-dioxolane) and high-modulus fluorinated products on the surface of Li-MSiOx particles. The LiF-rich SEI not only maintains the structural integrity of the Li-MSiOx particles, but also enhances the reversibility of Li storage in the Li-MSiOx anode.

CHEMICAL COMMUNICATIONS (2022)

Add to Collection

Article Nanoscience & Nanotechnology

Constructing Robust Cross-Linked Binder Networks for Silicon Anodes with Improved Lithium Storage Performance

Zhiming Zheng et al.

Summary: A novel binder-grafting strategy was proposed to construct Si-CMC/PA electrodes with high reversible capacity and improved long-term cycling stability; in situ transmission electron microscopy revealed the binding effect of CMC/PA on the silicon anode, effectively preventing cracking; combined microscopy and X-ray photoelectron spectroscopy analysis unveiled the superior Li-ion storage performance origin of Si-CMC/PA electrodes.

ACS APPLIED MATERIALS & INTERFACES (2021)

Add to Collection

Review Chemistry, Multidisciplinary

Microscale Silicon-Based Anodes: Fundamental Understanding and Industrial Prospects for Practical High-Energy Lithium-Ion Batteries

Guanjia Zhu et al.

Summary: This review discusses the challenges in bridging the gap between industrial application and scientific research in Si-based batteries. Microscale design of Si-based electrodes with densified microstructure is seen as a key solution. Additionally, practical metrics and improvement strategies beyond active material are explored.

ACS NANO (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Gradient H-Bonding Binder Enables Stable High-Areal-Capacity Si-Based Anodes in Pouch Cells

Linlin Hu et al.

Summary: This study introduces a gradient hydrogen-bonding binder for silicon-based anodes in lithium-ion batteries, which effectively alleviates stress and prevents structure fracture, resulting in stable high-areal-capacity electrodes. The silicon-based pouch cell utilizing this binder demonstrates an impressive capacity retention of 80.2% after 700 cycles, showing great potential for practical applications.

ADVANCED MATERIALS (2021)

Add to Collection

Article Nanoscience & Nanotechnology

Improving the Electrochemical Property of Silicon Anodes through Hydrogen-Bonding Cross-Linked Thiourea-Based Polymeric Binders

Wen-Feng Ren et al.

Summary: In this study, hydrogen-bonding cross-linked thiourea-based polymeric binders (denoted CMC-co-SN) were designed and prepared for Si anodes. These binders, formed through in situ thermopolymerization, create a tight and physical interlocked layer with the Cu current collector, significantly improving the electrochemical performance of Si anodes by enhancing binding forces and maintaining electrode integrity. The results show high initial Coulomb efficiency and excellent cyclability for both micro- and nano-sized Si particles when using these binders.

ACS APPLIED MATERIALS & INTERFACES (2021)

Add to Collection

Article Chemistry, Physical

A robust network binder via localized linking by small molecules for high-areal-capacity silicon anodes in lithium-ion batteries

Zeheng Li et al.

Summary: A robust network binder (PG-c-ECH) is proposed to achieve stable cycling performance and high areal capacity of silicon anode by localized linking. The binder, rich in hydroxyl and carboxyl groups, ensures strong binding affinity between peach gum and silicon, while the introduced chemical crosslinker further enhances the localized linking for the polymer chains, resulting in durable interfacial adhesion and outstanding mechanical properties.

NANO ENERGY (2021)

Add to Collection

Article Chemistry, Physical

In-Situ Polymerized Binder: A Three-in-One Design Strategy for All-Integrated SiOx Anode with High Mass Loading in Lithium Ion Batteries

Shuxing Wu et al.

Summary: This study introduces a three-in-one design strategy for binder systems in SiOx electrodes, utilizing hard PFA and soft TPU interweaved in a 3D conformation to confine SiOx particles through in-situ polymerization. This collaborative approach results in an areal capacity of 2.4 mAh cm(-2) at a high mass loading of >3.0 mg cm(-2) after 100 cycles, and can be extended to other metal oxides anodes such as Fe2O3 and SnO2, shedding light on the rational design of functional polymer binders for high-areal-capacity electrodes.

ACS ENERGY LETTERS (2021)

Add to Collection

Review Chemistry, Multidisciplinary

Recent Advances in Silicon-Based Electrodes: From Fundamental Research toward Practical Applications

Mingzheng Ge et al.

Summary: This article presents the latest developments in the rational design of Si-based electrodes and their potential applications, while discussing the challenges and potential solutions. Si-based anode materials will play a key role in meeting the demands for higher energy density in the coming decades.

ADVANCED MATERIALS (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Designing Adaptive Binders for Microenvironment Settings of Silicon Anode Particles

Haesung A. Lee et al.

Summary: This study introduces the concept of an adaptive binder to tackle the silicon anode challenge in Li-ion batteries. The binder exhibits adaptable capabilities in response to gradual changes in the microenvironments surrounding silicon particles, with reversible and irreversible chemical interactions stabilizing adhesion to the silicon particle surfaces. The adaptive properties of the binder contribute to maintaining a higher charge capacity after repeated battery cycles, highlighting the importance of adaptability in designing silicon-anode binders.

ADVANCED MATERIALS (2021)

Add to Collection

Review Engineering, Environmental

Towards efficient binders for silicon based lithium-ion battery anodes

Yajun Yang et al.

Summary: This review provides a comprehensive analysis of existing and emerging binders for Si-based LIB anodes in terms of their structures, properties, advantages, limitations, working principles, design rules, and associated electrochemical mechanisms. It also offers a perspective on current challenges and research directions for commercializing Si-based anodes in the near future.

CHEMICAL ENGINEERING JOURNAL (2021)

Add to Collection

Article Chemistry, Physical

A carboxymethyl vegetable gum as a robust water soluble binder for silicon anodes in lithium-ion batteries

Zechen Wang et al.

Summary: Research shows that modified guar gum CMGG as a binder for silicon anodes effectively solves the issue of volume changes in silicon particles, maintaining high capacity and reversibility. The CMGG binder also promotes lithium-ion transport, reduces electrode polarization, and helps enhance the electrochemical stability of silicon anodes at high current density.

JOURNAL OF POWER SOURCES (2021)

Add to Collection

Article Chemistry, Physical

A mechanically robust self-healing binder for silicon anode in lithium ion batteries

Hao Chen et al.

Summary: Silicon is considered the most promising anode material for next-generation lithium ion batteries, but silicon particles undergo volume changes and pulverization during charge/discharge processes, damaging the longevity of silicon anodes. This study synthesized a novel self-healing binder to repair the damage to silicon anodes, achieving excellent electrochemical performance.

NANO ENERGY (2021)

Add to Collection

Article Nanoscience & Nanotechnology

In Situ-Formed Novel Elastic Network Binder for a Silicon Anode in Lithium-Ion Batteries

Zhimeng Liu et al.

Summary: A polymer binder with a unique network structure was developed to address the volume fluctuation issue of silicon anode in lithium-ion batteries, effectively improving the cycle stability and rate performance of the battery.

ACS APPLIED MATERIALS & INTERFACES (2021)

Add to Collection

Article Engineering, Environmental

Design of high-energy-dissipation, deformable binder for high-areal-capacity silicon anode in lithium-ion batteries

Linlin Hu et al.

Summary: By synergizing static and dynamic binders, an efficient energy-dissipation engineering was applied to high-capacity silicon anodes, effectively improving their cycling stability and capacity retention. This strategy successfully avoids degradation of both materials and electrodes, laying the foundation for performance enhancement of silicon-based anodes.

CHEMICAL ENGINEERING JOURNAL (2021)

Add to Collection

Article Materials Science, Multidisciplinary

Low-cost and scalable preparation of nano-Si from photovoltaic waste silicon for high-performance Li-ion battery anode

Shiyun Zhang et al.

Summary: The study presents a facile, scalable, and cost-effective method to produce high-performance nano-Si using cheap Si sources from PV waste. The resulting nano-Si exhibits superior performance with higher Coulombic efficiency and better cycling stability compared to commercial nano-Si. This work provides a promising and sustainable approach to utilizing low-cost Si sources for high-performance nano-Si production.

FUNCTIONAL MATERIALS LETTERS (2021)

Add to Collection

Article Chemistry, Physical

Novel constructive self-healing binder for silicon anodes with high mass loading in lithium-ion batteries

Yong Wang et al.

Summary: The elastic self-healing CA-PAA binder designed for silicon anodes can accommodate large volume changes and maintain high performance during cycling.

ENERGY STORAGE MATERIALS (2021)

Add to Collection

Article Chemistry, Physical

Multiple Network Binders via Dual Cross-Linking for Silicon Anodes of Lithium-Ion Batteries

Xingxing Jiao et al.

Summary: A novel water-soluble three-dimensional network polymer binder has been reported for silicon anode in lithium-ion batteries, which can effectively address the volume expansion issue and demonstrate excellent electrochemical performance under high rates.

ACS APPLIED ENERGY MATERIALS (2021)

Add to Collection

Article Chemistry, Physical

Understanding why poly(acrylic acid) works: decarbonylation and cross-linking provide an ionically conductive passivation layer in silicon anodes

Trevor R. Martin et al.

Summary: This study reveals the evolution of PAA during electrode fabrication and its impact on electrode performance using in situ spectroscopy techniques. The results show that PAA undergoes a chemical change to form a polyether network polymer during cross-linking reaction. Additionally, PAA acts as an interfacial material that conducts lithium ions, limits solvent molecule access to the Si surface, and stabilizes the electrode against parasitic lithium inventory loss.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Add to Collection

Review Materials Science, Multidisciplinary

Advances of polymer binders for silicon-based anodes in high energy density lithium-ion batteries

Yu-Ming Zhao et al.

Summary: Polymer binders play a critical role in alleviating volume expansion and maintaining the integrity and stable cycling of Si-based anodes, contributing to the practical application of high-capacity anodes in lithium-ion batteries.

INFOMAT (2021)

Add to Collection

Article Chemistry, Multidisciplinary

A perspective on sustainable energy materials for lithium batteries

Xin-Bing Cheng et al.

Summary: Lithium-ion batteries have been successful in portable electronics and electric vehicles, but face challenges in terms of sustainable development, requiring innovation in material chemistry and safety performance, as well as the importance of battery recycling for a sustainable society.

SUSMAT (2021)

Add to Collection

Article Chemistry, Physical

Silicon Anode with High Initial Coulombic Efficiency by Modulated Trifunctional Binder for High-Areal-Capacity Lithium-Ion Batteries

Zeheng Li et al.

ADVANCED ENERGY MATERIALS (2020)

Add to Collection

Article Energy & Fuels

Electrolyte design for LiF-rich solid-electrolyte interfaces to enable high-performance microsized alloy anodes for batteries

Ji Chen et al.

NATURE ENERGY (2020)

Add to Collection

Article Chemistry, Physical

Ultra-efficient polymer binder for silicon anode in high-capacity lithium-ion batteries

Shilun Gao et al.

NANO ENERGY (2020)

Add to Collection

Review Chemistry, Physical

A Review of the Design of Advanced Binders for High-Performance Batteries

Feng Zou et al.

ADVANCED ENERGY MATERIALS (2020)

Add to Collection

Review Chemistry, Physical

Molecular design principles for polymeric binders in silicon anodes

Andrea Miranda et al.

MOLECULAR SYSTEMS DESIGN & ENGINEERING (2020)

Add to Collection

Review Chemistry, Physical

Commercialization of Lithium Battery Technologies for Electric Vehicles

Xiaoqiao Zeng et al.

ADVANCED ENERGY MATERIALS (2019)

Add to Collection

Review Materials Science, Multidisciplinary

A review of rechargeable batteries for portable electronic devices

Yeru Liang et al.

INFOMAT (2019)

Add to Collection

Review Chemistry, Multidisciplinary

The emerging era of supramolecular polymeric binders in silicon anodes

Tae-woo Kwon et al.

CHEMICAL SOCIETY REVIEWS (2018)

Add to Collection

Review Chemistry, Multidisciplinary

Silicon-Based Anodes for Lithium-Ion Batteries: From Fundamentals to Practical Applications

Kun Feng et al.

SMALL (2018)

Add to Collection

Article Multidisciplinary Sciences

Highly elastic binders integrating polyrotaxanes for silicon microparticle anodes in lithium ion batteries

Sunghun Choi et al.

SCIENCE (2017)

Add to Collection

Article Chemistry, Physical

Challenges and Recent Progress in the Development of Si Anodes for Lithium-Ion Battery

Yan Jin et al.

ADVANCED ENERGY MATERIALS (2017)

Add to Collection

Review Chemistry, Physical

Water Soluble Binder, an Electrochemical Performance Booster for Electrode Materials with High Energy Density

Jun-Tao Li et al.

ADVANCED ENERGY MATERIALS (2017)

Add to Collection

Review Chemistry, Physical

Silicon based lithium-ion battery anodes: A chronicle perspective review

Xiuxia Zuo et al.

NANO ENERGY (2017)

Add to Collection

Review Nanoscience & Nanotechnology

Promise and reality of post-lithium-ion batteries with high energy densities

Jang Wook Choi et al.

NATURE REVIEWS MATERIALS (2016)

Add to Collection

Article Chemistry, Physical

Improved Performance of the Silicon Anode for Li-Ion Batteries: Understanding the Surface Modification Mechanism of Fluoroethylene Carbonate as an Effective Electrolyte Additive

Chao Xu et al.

CHEMISTRY OF MATERIALS (2015)

Add to Collection

Review Chemistry, Physical

Silicon-based materials as high capacity anodes for next generation lithium ion batteries

Bo Liang et al.

JOURNAL OF POWER SOURCES (2014)

Add to Collection

Article Chemistry, Physical

A coordinatively cross-linked polymeric network as a functional binder for high-performance silicon submicro-particle anodes in lithium-ion batteries

Li Zhang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2014)

Add to Collection

Article Chemistry, Physical

Comparative Study of Sodium Polyacrylate and Poly(vinylidene fluoride) as Binders for High Capacity Si-Graphite Composite Negative Electrodes in Li-Ion Batteries

Shinichi Komaba et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2012)

Add to Collection

Article Chemistry, Multidisciplinary

A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes

Nian Liu et al.

NANO LETTERS (2012)

Add to Collection

Article Nanoscience & Nanotechnology

Stable cycling of double-walled silicon nanotube battery anodes through solid-electrolyte interphase control

Hui Wu et al.

NATURE NANOTECHNOLOGY (2012)

Add to Collection

Article Multidisciplinary Sciences

A Major Constituent of Brown Algae for Use in High-Capacity Li-Ion Batteries

Igor Kovalenko et al.

SCIENCE (2011)

Add to Collection

Letter Nanoscience & Nanotechnology

Toward Efficient Binders for Li-Ion Battery Si-Based Anodes: Polyacrylic Acid

Alexandre Magasinski et al.

ACS APPLIED MATERIALS & INTERFACES (2010)

Add to Collection

Article Multidisciplinary Sciences

Building better batteries

M. Armand et al.

NATURE (2008)

Add to Collection

Review Multidisciplinary Sciences

Issues and challenges facing rechargeable lithium batteries

JM Tarascon et al.

NATURE (2001)

Add to Collection

© Peeref 2019-2024. All rights reserved.