An Elastic Cross-Linked Binder for Silicon Anodes in Lithium-Ion Batteries with a High Mass Loading

Due to the urgent demand for lithium-ion batteries (LIBs) with a high energy density, silicon (Si) possessing an ultrahigh capacity has aroused wide attention. However, its practical application is seriously hindered by enormous volume changes of the Si anode during cycling. Developing novel binders suitable for the Si anode has proven to be an effective strategy to improve its electrochemical performance. Herein, we constructed a three-dimensional network binder, in which the polyacrylic acid (PAA) long chains are cross-linked with one kind of amino acid, lysine (Lys). The abundant polar groups in PAA/Lys enable it to tightly adhere to the Si particles via hydrogen bonds, and the cross-linked structure prevents irreversible slipping of the PAA chains upon volume variation of the particles. The Si used was obtained from a sustainable route by recycling photovoltaic waste silicon. With high elasticity and strong adhesion, the PAA/Lys binder can effectively keep the structural integrity of the Si electrode and improve its electrochemical performance. The Si electrode using the PAA/Lys binder exhibits a good cycling stability (1008 mAh g-1 at 2 A g-1 after 250 cycles). Even with a high mass loading of 3.03 mg cm-2, the Si anode can remain stable for 100 cycles at a high fixed areal capacity of 3.03 mAh cm-2. This work gives a practical method to make stable Si electrodes using sustainable Si source and environmentally friendly amino acid-based binders.

Automated summary

Due to the urgent demand for high-energy-density lithium-ion batteries (LIBs), silicon (Si) with an ultrahigh capacity has gained wide attention. However, the practical application of Si is hindered by the large volume changes during cycling. In this study, a three-dimensional network binder composed of polyacrylic acid (PAA) and lysine (Lys) was constructed. The PAA/Lys binder exhibited strong adhesion to Si particles through hydrogen bonds and the cross-linked structure prevented irreversible slipping of PAA chains. The Si electrode using the PAA/Lys binder showed good cycling stability and high capacity retention, demonstrating the potential of using sustainable Si sources and environmentally friendly binders.