Mo-Based Heterogeneous Interface and Sulfur Vacancy Synergistic Effect Enhances the Fenton-like Catalytic Performance for Organic Pollutant Degradation

Heterogeneous Fenton-like reactions (HFLRs) based on the in situ electrochemical generation of hydrogen peroxide (H2O2) are one of the green methods to remediate organic pollutants in wastewater. However, the design of Fenton-like catalysts with specific active sites and high pollutant degradation rate is still challenging. Here, MoS2-MoC and MoS2-Mo2N catalytic cathodes with heterojunctions were successfully prepared, and the mechanism by which hydroxyl radicals and singlet oxygen (1O2) were generated cleanly without adding chemical additives other than oxygen was clarified. The composite catalysts contained more sulfur vacancies, and the catalytic cathode achieved a high paracetamol pollutant degradation efficiency with 0.17 kWh g-1 TOC specific energy consumption. And almost 5 times higher activity was achieved compared to a pure MoS2 catalytic cathode. Experimental studies confirmed that the production of 1O2 was based on the transformation of superoxide radicals by Mo6+ , and 1O2 accounted for approximately 66% of the total degradation and enhanced the nonradical behavior in the reaction. This work provides a sustainable strategy for pollutant utilization, which is valuable for solving the difficult problems of HFLRs and developing new environmental remediation technologies.

Automated summary

Heterogeneous Fenton-like reactions based on MoS2-MoC and MoS2-Mo2N catalytic cathodes achieved high pollutant degradation efficiency and clarified the mechanism of hydroxyl radicals and singlet oxygen generation. The composite catalysts with more sulfur vacancies exhibited 5 times higher activity compared to pure MoS2 cathode. The production of singlet oxygen was based on the transformation of superoxide radicals by Mo6+ and accounted for 66% of the total degradation. This work provides a sustainable strategy for pollutant utilization and has significant value for developing new environmental remediation technologies.