Journal
JOURNAL OF NATURAL PRODUCTS
Volume 80, Issue 1, Pages 108-113Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jnatprod.6b00754
Keywords
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Funding
- Natural Sciences Foundation of Yunnan Province [2015FA032, 2016FB017]
- Foundation of State Key Laboratory of Phytochemistry and Plant Resources in West China [P2015-ZZ07]
- Foundation from Youth Innovation Promotion Association CAS
- West Light Foundation of the Chinese Academy of Sciences
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The previous assignment of the type C skeleton of polycyclic polyprenylated acylphloroglucinols (PPAPs) was controversial and proved to be incorrect in this study. The structures of the type C PPAPs (3-6) were revised to corresponding type A structures (3a-6a) via C-13 NMR spectroscopic analysis and a quantum computational chemistry method. Therefore, only types A and B PPAPs are likely present in plants of the family Clusiaceae.
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