h-BN-TiO2 Nanocomposite for Photocatalytic Applications

h-BN-TiO2 nanocomposites were synthesized by the thermal hydrolysis of titanium peroxo-complexes in the presence of exfoliated h-BN. The bulk h-BN was prepared by annealing mixture of boric acid and urea, and high intensity ultrasound was used for its exfoliation. The prepared samples were characterized by X-ray powder diffraction (XRD), infrared spectroscopy, Raman spectroscopy, electron spin resonance (ESR), high resolution electron microscopy, BET surface area, and BJH porosity measurement. The UV-Vis diffuse reflectance spectroscopy was employed to estimate band-gap energies. The photoinduced charge on the surface of h-BN-TiO2 nanocomposites was visualized using electric force microscopy (EFM). The photocatalytic activity was determined by azo dyes Orange II and Reactive Black 5 photobleaching. The highest rate constant.. = 0.0762 min(-1) and 0.0164 min(-1), under UV and visible light irradiation, respectively, showed sample denoted TiP050BN with moderate concentration of h-BN.