Journal
JOURNAL OF MOLECULAR LIQUIDS
Volume 213, Issue -, Pages 28-32Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molliq.2015.11.004
Keywords
Air/water interface; Bulk water; Hydrogen bonding; SFG; Raman
Funding
- National Natural Science Foundation of China [41373057]
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Vibrational sum frequency generation (SFG) spectroscopy is employed to investigate the water structure at an air/water interface. By obtaining the SFG intensity using different polarizations, it is reasonable to deconvolute the conventional SFG spectrum into five sub -bands, which are located at 3100, 3200, 3400, 3550 and 3700 cm(-1). In comparison with the Raman OH stretching bands of liquid water, we suggest that the five fitted sub -bands can be attributed to OH vibrations engaged in various local hydrogen-bonded networks, such as single donor-double acceptor (DAA), double donor-double acceptor (DDAA), single donor-single acceptor (DA), double donor-single acceptor (DDA), and free-OH vibrations, respectively. Owing to the truncations of hydrogen bonds at the air/water interface, obvious structural differences between interfacial water and bulk water can be expected. For ambient water, both DA and DDAA are the primary hydrogen-bonded networks. By contrast, DA hydrogen bonding can be regarded as the primary structural motif at the air/water interface. Additionally, we suggest that the loss of DDAA hydrogen bonding at the air/water interface provides the physical origin of surface tension, which can be applied to understand the formation of a water droplet. (C) 2015 Elsevier B.V. All rights reserved.
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