Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 414, Issue -, Pages 94-107Publisher
ELSEVIER
DOI: 10.1016/j.molcata.2016.01.006
Keywords
Mesocellular foam; Fe loading; Catalysts characteristics; Catalytic degradation; Catalyst reusability
Categories
Ask authors/readers for more resources
Fe incorporated mesocellular foam catalysts (FeMCFs) developed by direct synthesis method were characterized and catalytic degradation of acid red B dye (ARB) via Fenton-like reaction was demonstrated. The shape and particle sizes of FeMCF changed significantly with an increase in the Fe concentration (4-12 wt.%) accompanied with the formation of Fe particles agglomerated on the external surface of the catalysts. Interestingly, the sponge-like foam structure coupled with large pores of MCF could be maintained for all concentrations of Fe added. FT-IR and UV-vis DRS analyses revealed that Fe was successfully incorporated mostly within the mesostructure of MCF rather than being distributed on the external surface at Fe loadings of 4-10 wt.%. However, formation of minor amount of iron oxides distributed on the external surface of FeMCF12 was detected by the appearance of broad bands in the range of 300-400 nm. An increase in the Fe content (4-12 wt.%) gave a slight decrease in the surface area (708-606 m(2)/g) and pore properties of the FeMCF. The increase in the Fe concentration from 4 to 12 wt.% progressively increased the degradation from 63 to 100%. The high decolourisation and degradation efficiencies of FeMCF10 could be explained in terms of combined factors such as high mesopore surface area (552 m(2)/g), large cell size (8 nm) and the presence of isolated Fe species leading to high accessibility of active sites without mass transfer limitations. FeMCF10 exhibited long term stability and good structural stability after it was used for five consecutive degradation cycles. (C) 2016 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available