Mechanism of pyridine bases prepared from acrolein and ammonia by in situ infrared spectroscopy

The in situ infrared spectroscopy of acrolein and ammonia over HF/MgZSM-5 was investigated to check the adsorption reaction of acrolein and ammonia. It was proved that propylene imine intermediate came up during the condensation process of adsorbed acrolein with ammonia. The strong adsorption of C=O helps the formation of propylene imine. The reaction order and active energy were calculated according to the intensity of acrolein infrared spectroscopy. The synthesis of 3-picoline is likely to go through a flat adsorption of propylene imine and a deamination of amino dihydropyridine. (C) 2015 Published by Elsevier B.V.