Layer-by-Layer Heterostructure of MnO2@Reduced Graphene Oxide Composites as High-Performance Electrodes for Supercapacitors

In this paper, delta-MnO2 with layered structure was prepared by a facile liquid phase method, and exfoliated MnO2 nanosheet (e-MnO(2)was obtained by ultrasonic exfoliation, whose surface was negatively charged. Then, positive charges were grafted on the surface of MnO2 nanosheets with a polycation electrolyte of polydiallyl dimethylammonium chloride (PDDA) in different concentrations. A series of e-MnO2@reduced graphene oxide (rGO) composites were obtained by electrostatic selfassembly combined with hydrothermal chemical reduction. When PDDA was adjusted to 0.75 g/L, the thickness of e-MnO2 was similar to 1.2 nm, and the nanosheets were uniformly adsorbed on the surface of graphene, which shows layer-by-layer morphology with a specific surface area of similar to 154 m(2)/g. On account of the unique heterostructure, the composite exhibits good electrochemical performance as supercapacitor electrodes. The specific capacitance of e-MnO2 -0.75@rGO can reach 456 F/g at a current density of 1 A/g in KOH electrolyte, which still remains 201 F/g at 10 A/g. In addition, the capacitance retention is 98.7% after 10000 charge-discharge cycles at 20 A/g. Furthermore, an asymmetric supercapacitor (ASC) device of e-MnO2-0.75@rGO//graphene hydrogel (GH) was assembled, of which the specific capacitance achieves 94 F/g (1 A/g) and the cycle stability is excellent, with a retention rate of 99.3% over 10000 cycles (20 A/g).

Automated summary

In this study, layered delta-MnO2 was prepared by a liquid phase method, and a composite of e-MnO2@rGO with unique structure was obtained. The electrochemical performance of the composite was investigated, demonstrating high specific capacitance and excellent cycle stability.