Pt-N Co-Modified TiO2 Nanotube Electrode Photoelectrocatalytic Degradation of Oxytetracycline in Simulated Wastewater

Using photodeposition and plasma, Pt-N co-modified TiO2 nanotube electrodes were created. Several techniques, such as SEM, XRD, UV-VIS-DRS, XPS, and PL, were used to analyze the electrode shape, crystalline structure, light absorption range, elemental composition, and photo-generated carrier recombination efficiency. Using the electrochemical workstation, EIS and I-t were utilized to examine the electrochemical characteristics. The results indicated that the diameter of the TiO2 nanotube tubes was around 90 nm, and that the photodeposition duration affected the amount of Pt particles deposited. The deposited Pt particles efficiently reduced the photogenerated carrier complexation rate of the N-TiO2 nanotube electrode, contributing to the separation of electron-hole pairs and light utilization. Electrochemical studies indicated that Pt-N co-modified TiO2 increased the electrode's oxidation and electrical conductivity, as well as its photoelectrocatalytic capacity. Oxytetracycline degradation in simulated wastewater by a Pt-N co-modified TiO2 nanotube electrode revealed the exceptional PEC activity, and the oxytetracycline degradation processes followed primary kinetics. center dot O-2(-) and center dot OH played a significant role in the photoelectrocatalytic degradation of oxytetracycline, resulting in a novel method for oxytetracycline degradation.

Automated summary

In this study, Pt-N co-modified TiO2 nanotube electrodes were created using photodeposition and plasma. The electrodes were characterized using various techniques, and the results showed that the Pt-N co-modified TiO2 electrodes exhibited excellent photoelectrocatalytic activity and conductivity, making them suitable for oxytetracycline degradation in wastewater.