4.7 Article

Rapid joule-heating activation boosted capacitive performance of carbon fibers

Journal

COMPOSITES COMMUNICATIONS
Volume 34, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.coco.2022.101263

Keywords

Joule -heating; Activation; Carbon fiber; Capacitance

Funding

  1. National Natural Science Foundation of China [52102040, 51903212]
  2. Fundamental Research Funds for the Central Universities [JZ2022HGTB0280]
  3. University Synergy Innovation Program of Anhui Province [GXXT-2019-016]

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This paper presents a fast and environmentally friendly method to activate carbon fibers (CFs) using a one-step joule-heating process. The activated CFs exhibit a hierarchically porous structure and exfoliated surface layers. As a fiber electrode, it shows a specific capacitance of 162 F g-1, which is 125 times higher than that of non-activated CFs. Furthermore, the joule-heating activation promotes the growth of foreign components on the fiber surface and enhances their interfacial interaction.
The traditional activation methods for carbon fibers (CFs) such as strong acid etching are corrosive, time consuming and heavily polluting. In this paper, we report a fast and environment-friendly method to activate CF by a one-step joule-heating process. With only 10 min treatment, the oxygen content in the fiber surface reaches to 24.6%, and the activated CF with hierarchically porous structure and exfoliated surface layers is obtained. As a fiber electrode, it reveals a specific capacitance of 162 F g-1, which is 125 times of the non-activated CF. Furthermore, the joule-heating activation also facilitates the growth of foreign component on fiber surface and strengthens their interfacial interaction. This work provides a novel approach for the rapid fabrication and functionalization of CF-based devices and composites.

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