Journal
JOURNAL OF MEMBRANE SCIENCE
Volume 505, Issue -, Pages 138-147Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.memsci.2016.01.036
Keywords
Imidazolium; Anion-exchange membrane; Alkaline stability; Alkaline fuel cells
Categories
Funding
- National Natural Science Foundation of China [51273024, 51303015]
- Department of Education of Jilin Province [2014119]
- Scientific and Technological Planning Projects of the Jilin Province [20130101021JC]
- Program for New Century Excellent Talents in University of Ministry of Education of China
Ask authors/readers for more resources
A facile functionalized routine was designed for the synthesis of novel imidazolium-based poly(ether sulfone) (Im-PES) anion-exchange membrane (AEM). The special matrix, a type of PES with double bonds (PES-DB), was chosen to react directly with the functional reagent, 1-allyl-3-methylimidazolium chloride (AmimCl). This method eliminates the disadvantages of conventional functionalized approaches, in which PES matrix should be pre-treated by chloromethylation or bromination reactions, making the whole routine complex and inefficient. Then, the structures and properties of the membranes were investigated. Apart from the stable structure and electrochemical performances, the alkaline stability was attractive. The membrane presents a high ionic conductivity (up to 9.21 x 10(-2) S cm(-1)) with a low methanol permeability (as low as 1.56 x 10(-7) cm(2) s(-1)). What is more, it can still retain around 83.6% of the initial ionic conductivity after treated in alkaline condition for 300 h. These results indicate that the simple functionalized routine is effective to synthesize the Im-PES and the membrane may possess potential applications for alkaline fuel cells (AFCs). (C) 2016 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available