Detection of Saffron's Main Bioactive Compounds and Their Relationship with Commercial Quality

This review aims to evaluate the state of saffron's main bioactive compounds and their relationship with its commercial quality. Saffron is the commercial name for the dried red stigmas of the Crocus sativus L. flower. It owes its sensory and functional properties mainly to the presence of its carotenoid derivatives, synthesized throughout flowering and also during the whole production process. These compounds include crocin, crocetin, picrocrocin, and safranal, which are bioactive metabolites. Saffron's commercial value is determined according to the ISO/TS3632 standard that determines their main apocatotenoids. Other techniques such as chromatography (gas and liquid) are used to detect the apocarotenoids. This, together with the determination of spectral fingerprinting or chemo typing are essential for saffron identification. The determination of the specific chemical markers coupled with chemometric methods favors the discrimination of adulterated samples, possible plants, or adulterating compounds and even the concentrations at which these are obtained. Chemical characterization and concentration of various compounds could be affected by saffron's geographical origin and harvest/postharvest characteristics. The large number of chemical compounds found in the by-products (flower parts) of saffron (catechin, quercetin, delphinidin, etc.) make it an interesting aromatic spice as a colorant, antioxidant, and source of phytochemicals, which can also bring additional economic value to the most expensive aromatic species in the world.

Automated summary

This review evaluates the main bioactive compounds of saffron and their relationship with its commercial quality. Saffron's commercial value is determined by the presence of carotenoid derivatives, such as crocin, crocetin, picrocrocin, and safranal. Chemometric methods, coupled with chemical markers, can be used to detect adulterated samples and determine their concentrations. Geographical origin and harvest/postharvest characteristics can affect the chemical composition and concentration of compounds in saffron. Saffron's by-products also contain various chemical compounds that add to its value as an aromatic spice.