4.7 Article

Synergistic effect of La2o3 -Nio nanocomposite based electrode for electrochemical high-performance asymmetric supercapacitor applications

Journal

JOURNAL OF ENERGY STORAGE
Volume 53, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.est.2022.104988

Keywords

Specific capacitance; Thermal analysis; Rare earth metal; Cyclic voltammetry; Cyclic stability

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Funding

  1. UGC-SAP
  2. DST-FIST
  3. DST-PURSE
  4. MHRD-RUSA

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Global economic growth and rapid industrial development have led to a severe energy problem, necessitating the search for alternative and sustainable energy sources. Supercapacitors are among the most important energy storage devices, and the development of high-performance supercapacitor electrodes is currently a major research topic. This study presents the hydrothermal research results on rare earth-based La2O3-NiO-based electrodes for electrochemical supercapacitor applications, demonstrating their excellent performance.
Global economic growth and rapid industrial development have resulted in a severe energy problem. Renewable energy sources have been replaced by alternative and sustainable energy sources. Super capacitors are one of the most important types of energy storage devices. The development of supercapacitor electrodes with maximum performance is currently the most important research topic in this area. Here we present the results of hydrothermal research on rare earth-based nanocomposites of Lanthanum-Nickel La2O3 -NiO-based electrodes for electrochemical super capacitor applications. XRD, FTIR, TG/DTA, SEM, TEM and EDAX techniques are used to examine the physico-chemical characteristics such as crystallographic structure, vibrational characteristics, thermal stability morphology, chemical composition, and its features respectively. According to the cyclic voltammetry (CV) investigation, the prepared nanocomposite materials have a Specific capacitance of 704 F/g at scan rate of 5 mV/s. EIS analysis demonstrates the RsValues ofLa2O3 (0.11549 0) NiO(0.1937 0) La2O3 -NiO (0.641 0) increased conductivity of nanocomposite material. According to galvanostatic charge-discharge (GCD) tests, the La2O3 -NiO electrode has a maximum specific capacitance of 564 F/g at 1 A/g current density in 1 M KOH electrolyte. This result proved that the prepared (La2O3 -NiO Nanocomposite), electrode material used for practical application, which shows good capacitive retention of 93.4%even after 2000 cycles. More ever asymmetric device constructed superior cyclic stability of 77.2%of capacitive retention even after 2000 charge discharge cycle.

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