Supercapacitor applications of novel phosphorus doped graphene-based electrodes

In this study, the supercapacitor performances of phosphorus-containing functional groups doped graphene electrodes, which were synthesized in one step and environmentally by Yucel's method, were investigated. The formation of graphene layers in the mesopore structure was observed by scanning electron microscopy. Functional phosphorus and phosphorus including functional groups such as -[(-P2O7)](4-) and -(PO3-) formed on the electrode surface were characterized by X-ray photoelectron spectroscopy. Cyclic voltammetry and electrochemical impedance spectroscopy were used for electrochemical characterization of the electrodes. Cyclic charge-discharge tests were also done for 1000 cycles to determine the cyclic stability of electrode materials. As the number of cycles increased during the synthesis of the electrodes, the number of different molecular functional groups on the surface increased. In addition, due to the polyphosphate structures formed on the surface, the capacity increase occurred contrary to what was expected in the cyclic charge-discharge tests of the electrodes. The highest areal capacitance was determined as 301.3 mF.cm(-2) at the current density of 10 mA.cm(-2) for P3-GE50 in sulfuric acid solution.

Automated summary

This study investigated the supercapacitor performances of phosphorus-containing functional groups doped graphene electrodes synthesized in one step and environmentally by Yucel's method. Graphene layers in the mesopore structure were observed, and functional phosphorus and phosphorus including functional groups formed on the electrode surface were characterized. Electrochemical characterization and cyclic charge-discharge tests were performed to determine the cyclic stability and capacitive properties of the electrodes. Results showed an increase in the number of different molecular functional groups on the electrode surface with the number of cycles, and the capacity increase in contrary to expectations due to the formation of polyphosphate structures. The highest areal capacitance was determined as 301.3 mF.cm(-2) for P3-GE50 at 10 mA.cm(-2) current density in sulfuric acid solution.