4.6 Article

Effect of a Discontinuous Ag Layer on Optical and Electrical Properties of ZnO/Ag/ZnOStructures

Journal

COATINGS
Volume 12, Issue 9, Pages -

Publisher

MDPI
DOI: 10.3390/coatings12091324

Keywords

transparent conductive oxide (TCO); magnetron sputtering; ZnO; Ag; ZnO; transparent conducting nanolaminate structures; discontinuous Ag layer; oxide; metal; oxide

Funding

  1. Operational Programme Science and Education For Smart Growth 2014-2020 - EU from European Regional Development Fund [BG05M2OP001-1.0020014]

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ZnO/Ag/ZnO nanolaminate structures were deposited by RF sputtering at room temperature, and the optical and electrical properties were improved by the deposition of the discontinuous Ag layer. The presence of discrete Ag nano-granules was confirmed by atomic force microscopy and cross-section high-resolution transmission electron microscopy observations.
ZnO/Ag/ZnO nanolaminate structures were deposited by consecutive RF sputtering at room temperature.The optical transparency, sheet resistance, and figure of merit are determined in relation to the deposition time of Ag and to the film thickness of the ZnO top layer. An improved transmittance has been found in the visible spectral range of the ZnO/Ag/ZnO structure compared to ZnO multilayers without Ag. High transmittance of 98% at 550 nm, sheet resistance of 8 omega/sq, and figure of merit (FOM) of 111.01 x 10(-3) omega(-1)are achieved for an optimized ZnO/Ag/ZnO nanolaminate structure. It is suggested that the good optical and electrical properties are due to the deposition of the discontinuous Ag layer. The electrical metallic type conductivity is caused by planar located silver metal granules. The deposition of a discrete layer of Ag nano-granules is confirmed by atomic force microscopy (AFM) and cross-section high-resolution transmission electron microscopy (HRTEM) observations.

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