4.7 Article

Effects of Mg contents on microstructures and second phases of as-cast Al-Zn-Mg-Cu alloys

Journal

JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
Volume 21, Issue -, Pages 2105-2117

Publisher

ELSEVIER
DOI: 10.1016/j.jmrt.2022.10.050

Keywords

Al-Zn-Mg-Cu alloys; Microstructure evolution; Second phase; Nonequilibrium eutectic structure

Funding

  1. Major Science and Technology Project of Yunnan Province
  2. Key Research Development Program of Yunnan Province
  3. Yunnan Ten Thousand Talents Plan Young & Elite Talents Project
  4. Innovation Team Cultivation Project of Yunnan Province
  5. [202002AB080001-4]
  6. [202103AA080017]
  7. [CBN21281004A]
  8. [YNWR-QNBJ-2020-020]
  9. [202005AE160016]

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Increasing Mg content in the as-cast Al-Zn-Mg-Cu alloys leads to higher amounts of nonequilibrium eutectic structures and tertiary dendrites in the a(Al) matrix. Additionally, the crystallization temperature range decreases with increasing Mg content.
The effects of Mg content on the microstructures and second phases of the as-cast Al-Zn-Mg-Cu alloys were investigated. The results show that the nonequilibrium eutectic structure consists of a(Al), Al7Cu2Fe, h(MgZn2) and T(AlCuMgZn) intermetallic compounds. The alloys with the highest Mg content generate nonequilibrium eutectic structures. The maximum value of nonequilibrium eutectic structures is 10.13 +/- 0.62%. As the Mg content increases, the number of tertiary dendrites in the a(Al) matrix increases significantly, and more Mg can be dissolved into the Al-matrix. In addition, as the Mg content increases, the crystallization temperature range decreases from 169.8 K to 157.3 K. When the Mg content is higher than 2.6 wt%, the microstructure evolution of the Al-Zn-Mg-Cu aluminum alloy is as follows: Liq.-> Liq. + a(Al)-> Liq. + a(Al) + Al7Cu2Fe-> a(Al) + Al7Cu2Fe + h(MgZn2)-+ T(AlCuMgZn). These results play a certain role in promoting the basic research of Al-Zn-Mg-Cu aluminum alloys with high Mg content. (c) 2022 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

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