4.6 Review

Colloidal nanomaterials for water quality improvement and monitoring

Journal

FRONTIERS IN CHEMISTRY
Volume 10, Issue -, Pages -

Publisher

FRONTIERS MEDIA SA
DOI: 10.3389/fchem.2022.1011186

Keywords

colloids; nanomaterials; surface chemistry; inorganic nanoparticles; water quality

Funding

  1. Portugal 2020 through European Regional Development Fund (ERDF) [CENTRO2020, CENTRO -01-0247-FEDER-181268, UIDB/50011/2020, UIDP/50011/2020, LA/P/0006/2020, UIDB/50017/2020 + UIDP/50017/2020 + LA/P/0094/2020]
  2. FCT/MEC (PIDDAC) - Portugal 2020 through the European Regional Development Fund (ERDF) [POCI-01-0247-FEDER- 017729]
  3. Fundacao para a Ciencia e Tecnologia (FCT) [PD/BD/150568/2020, SFRH/BD/131433/2017]
  4. European Union [101065059, -078 - 88 -ARH/2018, REF.-069-88-ARH/2018, 57/2016, 57/2017]
  5. FCT [CEECIND/03739/2021]
  6. Marie Curie Actions (MSCA) [101065059] Funding Source: Marie Curie Actions (MSCA)

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This article reviews literature on the development of nanomaterials for water purification technologies and presents collaborative scientific research carried out in the laboratory. The research focuses on the synthesis and surface chemical modification of nanomaterials, as well as the evaluation of their properties for applications in water treatment. The article discusses three thematic lines of research: magnetic nanosorbents, nanocomposites for photocatalysis, and nanostructured substrates for contaminant detection. The research is motivated by the belief that nanomaterials have the potential to contribute to environmental solutions without causing further harm.
Water is the most important resource for all kind forms of live. It is a vital resource distributed unequally across different regions of the globe, with populations already living with water scarcity, a situation that is spreading due to the impact of climate change. The reversal of this tendency and the mitigation of its disastrous consequences is a global challenge posed to Humanity, with the scientific community assuming a major obligation for providing solutions based on scientific knowledge. This article reviews literature concerning the development of nanomaterials for water purification technologies, including collaborative scientific research carried out in our laboratory (nanoLAB@UA) framed by the general activities carried out at the CICECO-Aveiro Institute of Materials. Our research carried out in this specific context has been mainly focused on the synthesis and surface chemical modification of nanomaterials, typically of a colloidal nature, as well as on the evaluation of the relevant properties that arise from the envisaged applications of the materials. As such, the research reviewed here has been guided along three thematic lines: 1) magnetic nanosorbents for water treatment technologies, namely by using biocomposites and graphite-like nanoplatelets; 2) nanocomposites for photocatalysis (e.g., TiO2/Fe3O4 and POM supported graphene oxide photocatalysts; photoactive membranes) and 3) nanostructured substrates for contaminant detection using surface enhanced Raman scattering (SERS), namely polymers loaded with Ag/Au colloids and magneto-plasmonic nanostructures. This research is motivated by the firm believe that these nanomaterials have potential for contributing to the solution of environmental problems and, conversely, will not be part of the problem. Therefore, assessment of the impact of nanoengineered materials on eco-systems is important and research in this area has also been developed by collaborative projects involving experts in nanotoxicity. The above topics are reviewed here by presenting a brief conceptual framework together with illustrative case studies, in some cases with original research results, mainly focusing on the chemistry of the nanomaterials investigated for target applications. Finally, near-future developments in this research area are put in perspective, forecasting realistic solutions for the application of colloidal nanoparticles in water cleaning technologies.

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