4.5 Review

Small Molecules Containing Amphoteric Imidazole Motifs as Sensitizers for Dye-Sensitized Solar Cells: An Overview

Related references

Note: Only part of the references are listed.
Review Chemistry, Inorganic & Nuclear

β-Pyrrole functionalized porphyrins: Synthesis, electronic properties, and applications in sensing and DSSC

Bijesh Sekaran et al.

Summary: Porphyrin and its derivatives play an important role in light harvesting and electron transfer processes. By controlling the modification of the porphyrin core, the optical and electronic properties can be tuned to improve their efficiency in various applications. The fl-substituted porphyrins in dye sensitized solar cells (DSSCs) are less explored due to synthetic difficulties. This review focuses on the synthetic aspects of fl-functionalized porphyrins, providing a better understanding of their electronic properties, sensing ability, and device performances in DSSCs.

COORDINATION CHEMISTRY REVIEWS (2022)

Article Chemistry, Applied

Long-lived cyclometallated iridium complexes: Synthesis, structure, DFT and photocatalytic aspects

Paltan Laha et al.

Summary: This study presents the synthesis, photophysical, and photocatalytic properties of four mononuclear luminescent iridium complexes. The complexes exhibit moderately good luminescent behavior with emission in the orangered region and show efficacy towards azo dye degradation in aqueous solution through the generation of reactive species under light irradiation.

DYES AND PIGMENTS (2022)

Article Chemistry, Inorganic & Nuclear

Sensitized and Self-Sensitized Photocatalytic Carbon Dioxide Reduction Under Visible Light with Ruthenium Catalysts Shows Enhancements with More Conjugated Pincer Ligands

Sanjit Das et al.

Summary: A new method for synthesizing complexes of the type [(CNC)Ru-II(NN)L](n+) has been introduced and a series of six new complexes have been characterized. The study shows that catalysts with benzimidazole derived CNC pincers exhibit better activity in photocatalysis, and a diimine ligand is required for self-sensitized photocatalysis.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2022)

Article Chemistry, Multidisciplinary

Effects of methoxy group(s) on D-π-A porphyrin based DSSCs: efficiency enhanced by co-sensitization

Devulapally Koteshwar et al.

Summary: A series of newly designed porphyrin sensitizers were studied for their photovoltaic performance, with those containing the cyanoacrylic acid anchoring group showing higher efficiency. Compared to LG18, sensitizers LG24 and LG26 with conjugated electron acceptors have advantages in terms of spectra and electronic structure.

MATERIALS CHEMISTRY FRONTIERS (2022)

Article Chemistry, Applied

Perspective on the rational design strategies of quinoxaline derived organic sensitizers for dye-sensitized solar cells (DSSC)

Gauravi Yashwantrao et al.

Summary: The incessant escalation of global energy consumption has led to a depletion of fossil fuel reserves. As a result, researchers have turned to solar energy as an unlimited source of energy. In particular, dye-sensitized solar cells (DSSC) have gained attention for their low-cost photovoltaic energy conversion and potential to meet global energy demand. This review article aims to provide an overview of the use of quinoxaline-based sensitizers in organic DSSCs and explore design strategies utilizing other electron-deficient heterocyclic scaffolds.

DYES AND PIGMENTS (2022)

Article Chemistry, Physical

Phenothiazine-based dyes containing imidazole with π-linkers of benzene, furan and thiophene: Synthesis, photophysical, electrochemical and computational investigation

Laila M. Nhari et al.

Summary: Three newly designed phenothiazine-based dyes were synthesized and their absorption and fluorescence properties were studied in different solvents. The dyes exhibited intense visible absorption and well-matched energy levels with reported sensitizers, making them potential candidates for use in photovoltaic devices.

JOURNAL OF MOLECULAR STRUCTURE (2022)

Review Green & Sustainable Science & Technology

Dye sensitized solar cells go beyond using perovskite and spinel inorganic materials: A review

Amin Alizadeh et al.

Summary: Inorganic perovskite and spinel materials show desirable characteristics and have the potential to be used as photoanode materials in DSSCs. The study demonstrates that employing certain amounts of perovskite or spinel materials can enhance the power conversion efficiency of fabricated DSSCs.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2022)

Review Energy & Fuels

Recent developments in metal-free organic sensitizers derived from carbazole, triphenylamine, and phenothiazine for dye-sensitized solar cells

Dheeraj Devadiga et al.

Summary: In the context of increasing population, the importance of renewable and sustainable energy alternatives is emphasized. Scientists are focusing on producing cost-effective and high-performance clean energy appliances to meet the growing demand. Dye-sensitized solar cells (DSSCs) are highlighted as a leading material in modern solar cell technologies, with metal-free organic dyes like carbazole (CZ), triphenylamine (TPA), and phenothiazine (PTZ) derivatives being identified as suitable alternatives to traditional complexes. This review primarily discusses the latest developments in using CZ, TPA, and PTZ scaffolds for DSSC applications, emphasizing the correlation between molecular design and photovoltaic performance. Adjusting the physical properties of devices through strategic sensitizer design can improve device performance, with photovoltaic parameters presented for all dyes and application insights on CZ, TPA, and PTZ-based dyes provided following a systematic review.

INTERNATIONAL JOURNAL OF ENERGY RESEARCH (2021)

Article Chemistry, Physical

Organic photosensitizers containing fused indole-imidazole ancillary acceptor with triphenylamine donor moieties for efficient dye-sensitized solar cells

Selvam Ramasamy

Summary: Controlling the morphology of sensitizer on a TiO2 nanocrystalline surface is crucial for enhancing electron injection and suppressing charge recombination, ultimately leading to improved performance of dye-sensitized solar cells.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

Article Chemistry, Applied

Advances in phenothiazine and phenoxazine-based electron donors for organic dye-sensitized solar cells

Sameera N. Al-Ghamdi et al.

Summary: Dye-sensitized solar cells (DSSCs) offer a cost-effective environmental solution for renewable energy production compared to traditional silicon solar cells. This review focuses on the importance of dye design and synthetic strategies for efficient dye chromophores in DSSCs, highlighting the impact of different factors on photovoltaic performance and discussing possibilities for improving spectral coverage and stability.

DYES AND PIGMENTS (2021)

Article Chemistry, Applied

Judicious design of L(D-π-A)2 type di-anchoring organic sensitizers for highly efficient dye-sensitized solar cells: Effect of the donor-linking bridges on functional properties

Zhihui Wang et al.

Summary: The development of two novel L(D-pi-A)(2) type di-anchoring sensitizers, W11-W12, with high photovoltaic performance, efficient light-harvesting, and enhanced self-anti-aggregation ability is reported. Rational adjustment of donor-linking bridges in these dyes results in significantly improved performance, particularly in suppressing interfacial charge recombination and achieving higher open-circuit voltage (V-oc) values. DSSCs sensitized by W12 exhibit a power conversion efficiency of 8.28% and an impressive Voc of 847 mV under standard AM 1.5 G illumination, making them among the highest efficiency cells of L(D-pi-A)(2) type di-anchoring organic dyes.

DYES AND PIGMENTS (2021)

Review Materials Science, Multidisciplinary

Enhancing spectral response towards high-performance dye-sensitised solar cells by multiple dye approach: A comprehensive review

Md. Akhtaruzzaman et al.

Summary: Dye-sensitized solar cells (DSSCs) are promising candidates for the latest solar cell technologies due to their low cost, flexibility, lightweight, and easy processing. Co-sensitization techniques have been studied to enhance light absorption and improve DSSC performance by mixing dyes, leading to significant advancements in the field.

APPLIED MATERIALS TODAY (2021)

Article Chemistry, Multidisciplinary

Prolonging the Triplet State Lifetimes of Rhenium Complexes with Imidazole-Pyridine Framework for Efficient CO2 Photoreduction

Li-Qi Qiu et al.

Summary: The study focuses on the photocatalytic reduction of CO2 into fuels using rhenium(I) tricarbonyl complexes. New mononuclear rhenium(I) tricarbonyl complexes based on the imidazole-pyridine skeleton were developed for this purpose, displaying phosphorescence even in Ar-saturated solution. Among them, a specific complex exhibited superior catalytic performance with high CO turnover number and selectivity, attributed to its strong visible light-harvesting ability and long-lived triplet lifetimes.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

Review Engineering, Multidisciplinary

A short review on the advancement in the development of TiO2 and ZnO based photo-anodes for the application of Dye-Sensitized Solar Cells (DSSCs)

Deepak Kumar

Summary: Population growth leads to expansion of areas and increased energy consumption, making solar energy an important option; dye-sensitized solar cells are popular due to their simplicity and low cost; improving DSSC performance can be achieved by altering the micro/nanostructure of the photo-electrodes.

ENGINEERING RESEARCH EXPRESS (2021)

Article Chemistry, Multidisciplinary

Imidazole substituted Zinc(ii) phthalocyanines for co-catalyst-free photoelectrochemical and photocatalytic hydrogen evolution: influence of the anchoring group

A. Celil Yuzer et al.

Summary: Novel zinc phthalocyanine derivatives with different numbers of imidazole units were synthesized and utilized as photosensitizers for photocatalytic H-2 evolution. The presence of one imidazole unit in ZnPc-1/TiO2 showed the best photoactivity with a high H-2 evolution rate, turnover number, and solar-to-hydrogen energy conversion efficiency.

CHEMICAL COMMUNICATIONS (2021)

Review Chemistry, Analytical

Imidazole Compounds: Synthesis, Characterization and Application in Optical Analysis

Junjie Wang et al.

Summary: Imidazole is a five-membered heterocyclic ring with unique optical properties, which has been increasingly used in optical analysis. It can form metal-organic frameworks and be utilized as fluorescence probes, colorimetric probes, etc. Future research may focus on developing imidazole sensors with high sensitivity and selectivity.

CRITICAL REVIEWS IN ANALYTICAL CHEMISTRY (2021)

Review Chemistry, Multidisciplinary

Dye-sensitized solar cells strike back

Ana Belen Munoz-Garcia et al.

Summary: Dye-sensitized solar cells (DSCs) and dye-sensitized photoelectrochemical cells (DSPECs) have seen a revival in recent years as they offer unique properties such as low cost, non-toxic materials, colorfulness, transparency, and efficiency in low light conditions. This review covers advancements in DSC technology over the past decade, including theoretical studies, characterization techniques, materials, applications, and commercialization efforts by various companies.

CHEMICAL SOCIETY REVIEWS (2021)

Review Materials Science, Multidisciplinary

Indole fused heterocycles as sensitizers in dye-sensitized solar cells: an overview

P. R. Nitha et al.

Summary: Extensive research has been conducted in the past three decades on developing non-metallic organic dyes for dye sensitized solar cells (DSSCs). Organic dyes have emerged as the most promising candidate for DSSCs due to their performance, easy synthesis, stability, low cost, and eco-friendly characteristics. Indole fused heterocycles have found wide applications as sensitizers in DSSCs, offering stability, ease of synthesis, and preventing sensitizer aggregation.

MATERIALS ADVANCES (2021)

Article Engineering, Electrical & Electronic

Design, Synthesis and Application of Imidazole-Based Organic Dyes in Dye Sensitized Solar Cells

Seyed Mohammad Javad Nabavi et al.

JOURNAL OF ELECTRONIC MATERIALS (2020)

Article Chemistry, Inorganic & Nuclear

Aromatic β-Diketone as a Novel Anchoring Ligand in Iridium(III) Complexes for Dye-Sensitized Solar Cells

Stanislav Bezzubov et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2020)

Article Chemistry, Inorganic & Nuclear

Robust nickel, manganese, and iron imidazole carboxylic acid catalysts for efficient visible-light driven reduction of CO2 to CO

Quan-Qing Xu et al.

INORGANIC CHEMISTRY COMMUNICATIONS (2020)

Review Chemistry, Inorganic & Nuclear

Amphiphilic photosensitizers in dye sensitized solar cells

Sujit Bhand et al.

INORGANICA CHIMICA ACTA (2019)

Review Materials Science, Multidisciplinary

Recent advances in dye-sensitized solar cells

V. Rondan-Gomez et al.

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING (2019)

Article Engineering, Electrical & Electronic

Synthesis and DSSC Applications of Ru(II) Complexes Bearing Benzimidazole Type Ligands

Melek Tercan et al.

JOURNAL OF ELECTRONIC MATERIALS (2019)

Article Materials Science, Multidisciplinary

Design and synthesis of imidazole-triphenylamine based organic materials for dye sensitized solar cells

S. Sambathkumar et al.

MATERIALS LETTERS (2019)

Article Chemistry, Physical

Novel Imidazole Substituted Bodipy-Based Organic Sensitizers in Dye-Sensitized Solar Cells

Mao Mao et al.

INTERNATIONAL JOURNAL OF PHOTOENERGY (2018)

Review Chemistry, Multidisciplinary

Recent Developments in AIEgens for Non-doped and TADF OLEDs

Fabio Rizzo et al.

ISRAEL JOURNAL OF CHEMISTRY (2018)

Review Materials Science, Multidisciplinary

Organic Light-Emitting Diodes Based on Imidazole Semiconductors

Wen-Cheng Chen et al.

ADVANCED OPTICAL MATERIALS (2018)

Article Chemistry, Organic

T-Shaped Benzimidazole Derivatives as Blue-Emitting Materials: The Role of C2 Substituents on Photophysical Properties

K. R. Justin Thomas et al.

ASIAN JOURNAL OF ORGANIC CHEMISTRY (2018)

Article Chemistry, Physical

New D-D '-A Configured Dye for Efficient Dye-Sensitized Solar Cells

Themmila Khamrang et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2018)

Review Materials Science, Multidisciplinary

Recent development of phenanthroimidazole-based fluorophores for blue organic light-emitting diodes (OLEDs): an overview

Jairam Tagare et al.

JOURNAL OF MATERIALS CHEMISTRY C (2018)

Article Materials Science, Multidisciplinary

Kinetics of dye regeneration in liquid electrolyte unveils efficiency of 10.5% in dye-sensitized solar cells

Jonnadula Venkata Suman Krishna et al.

JOURNAL OF MATERIALS CHEMISTRY C (2018)

Review Biochemical Research Methods

Porphyrin-Based Dye-Sensitized Solar Cells (DSSCs): a Review

Ozgul Birel et al.

JOURNAL OF FLUORESCENCE (2017)

Article Chemistry, Physical

Bulky Nature Phenanthroimidazole-Based Porphyrin Sensitizers for Dye-Sensitized Solar Cell Applications

Narra Vamsi Krishna et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2017)

Article Chemistry, Multidisciplinary

Thiocyanate-free ruthenium(II) sensitizers with a bi-imidazole ligand in dye-sensitized solar cells (DSSCs)

Saba Ashraf et al.

NEW JOURNAL OF CHEMISTRY (2017)

Article Chemistry, Multidisciplinary

Ferrocenyl benzimidazole with carboxylic and nitro anchors as potential sensitizers in dye-sensitized solar cells

Reena Yadav et al.

NEW JOURNAL OF CHEMISTRY (2017)

Article Materials Science, Multidisciplinary

Coumarin based sensitizers with ortho-halides substituted phenylene spacer for dye sensitized solar cells

Rohit L. Vekariya et al.

ORGANIC ELECTRONICS (2017)

Article Chemistry, Multidisciplinary

Effect of Donors on Photophysical, Electrochemical and Photovoltaic Properties of Benzimidazole-Branched Dyes

Govardhana Babu Bodedla et al.

ChemistrySelect (2017)

Article Chemistry, Multidisciplinary

Benzimidazole/Pyridoimidazole-Based Organic Sensitizers for High-Performance Dye-Sensitized Solar Cells

Sumit Chaurasia et al.

CHEMISTRY-AN ASIAN JOURNAL (2017)

Article Chemistry, Inorganic & Nuclear

Iridium(III) 2-Phenylbenzimidazole Complexes: Synthesis, Structure, Optical Properties, and Applications in Dye-Sensitized Solar Cells

Stanislav I. Bezzubov et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2016)

Article Chemistry, Multidisciplinary

Eugenic metal-free sensitizers with double anchors for high performance dye-sensitized solar cells

Wei-I Hung et al.

CHEMICAL COMMUNICATIONS (2015)

Article Chemistry, Organic

Imidazole-Based Sensitizers Containing Double Anchors for Dye-Sensitized Solar Cells

Yung-Sheng Yen et al.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2015)

Article Chemistry, Inorganic & Nuclear

New heteroleptic benzimidazole functionalized Ru-sensitizer showing the highest efficiency for dye-sensitized solar cells

T. Swetha et al.

INORGANIC CHEMISTRY COMMUNICATIONS (2015)

Article Materials Science, Multidisciplinary

Novel organic dyes based on phenyl-substituted benzimidazole for dye sensitized solar cells

Gozde Murat Saltan et al.

MATERIALS CHEMISTRY AND PHYSICS (2015)

Article Chemistry, Organic

N-Annulated Perylene-Based Push-Pull-Type Sensitizers

Qingbiao Qi et al.

ORGANIC LETTERS (2015)

Review Green & Sustainable Science & Technology

Recent improvements in dye sensitized solar cells: A review

Vipinraj Sugathan et al.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2015)

Article Spectroscopy

Impact of the different electron-releasing subunits on the dye-sensitized solar cell performance of new triphenylamine-benzimidazole based molecules

Haluk Dincalp et al.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2015)

Article Chemistry, Multidisciplinary

Cyclometalated ruthenium(II) complexes with bis(benzimidazolyl)benzene for dye-sensitized solar cells

Jiang-Yang Shao et al.

RSC ADVANCES (2015)

Article Chemistry, Organic

Triarylamine-Free Pyrenoimidazole-Containing Organic Dyes with Different π-Linkers for Dye-Sensitized Solar Cells

Dhirendra Kumar et al.

ASIAN JOURNAL OF ORGANIC CHEMISTRY (2015)

Review Materials Science, Multidisciplinary

Recent advances of the emitters for high performance deep-blue organic light-emitting diodes

Xiaolong Yang et al.

JOURNAL OF MATERIALS CHEMISTRY C (2015)

Article Chemistry, Organic

Organic Dyes Containing Fluorene Decorated with Imidazole Units for Dye-Sensitized Solar Cells

Dhirendra Kumar et al.

JOURNAL OF ORGANIC CHEMISTRY (2014)

Article Chemistry, Organic

Benzimidazole Derivatives: Selective Fluorescent Chemosensors for the Picogram Detection of Picric Acid

Jin-Feng Xiong et al.

JOURNAL OF ORGANIC CHEMISTRY (2014)

Review Green & Sustainable Science & Technology

Review on the development of natural dye photosensitizer for dye-sensitized solar cells

Norasikin A. Ludin et al.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2014)

Article Chemistry, Multidisciplinary

L-shaped benzimidazole fluorophores: synthesis, characterization and optical response to bases, acids and anions

Rio Carlo Lirag et al.

CHEMICAL COMMUNICATIONS (2013)

Review Chemistry, Multidisciplinary

Porphyrin-sensitized solar cells

Lu-Lin Li et al.

CHEMICAL SOCIETY REVIEWS (2013)

Article Chemistry, Inorganic & Nuclear

Sensing Hg(II) in Vitro and in Vivo Using a Benzimidazole Substituted BODIPY

Sheri Madhu et al.

INORGANIC CHEMISTRY (2013)

Article Materials Science, Multidisciplinary

Effect of imidazole derivatives in triphenylamine-based organic dyes for dye-sensitized solar cells

Linlei Zhou et al.

ORGANIC ELECTRONICS (2013)

Article Chemistry, Multidisciplinary

Molecular Shuttling of a Compact and Rigid H-Shaped [2]Rotaxane

Kelong Zhu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

Article Chemistry, Applied

New 2,6-modified BODIPY sensitizers for dye-sensitized solar cells

Mao Mao et al.

DYES AND PIGMENTS (2012)

Review Green & Sustainable Science & Technology

Review on dye-sensitized solar cells (DSSCs): Fundamental concepts and novel materials

Jiawei Gong et al.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2012)

Article Chemistry, Multidisciplinary

Liquid-Crystalline Perylene Diester Polymers with Tunable Charge-Carrier Mobility

Mathis-Andreas Muth et al.

ADVANCED FUNCTIONAL MATERIALS (2011)

Article Chemistry, Organic

Novel Pyrenoimidazole-Based Organic Dyes for Dye-Sensitized Solar Cells

Dhirendra Kumar et al.

ORGANIC LETTERS (2011)

Article Chemistry, Multidisciplinary

1-Alkyl-1H-imidazole-Based Dipolar Organic Compounds for Dye-Sensitized Solar Cells

Marappan Velusamy et al.

CHEMISTRY-AN ASIAN JOURNAL (2010)

Article Chemistry, Multidisciplinary

Di-branched di-anchoring organic dyes for dye-sensitized solar cells

Alessandro Abbotto et al.

ENERGY & ENVIRONMENTAL SCIENCE (2009)

Article Chemistry, Organic

Starburst triarylamine based dyes for efficient dye-sensitized solar cells

Zhijun Ning et al.

JOURNAL OF ORGANIC CHEMISTRY (2008)

Article Chemistry, Multidisciplinary

Molecular engineering of organic sensitizers for dye-sensitized solar cell applications

Daniel P. Hagberg et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2008)

Article Chemistry, Physical

Organic dyes containing 1H-phenanthro[9,10-d]imidazole conjugation for solar cells

Ming-Shan Tsai et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2007)

Article Physics, Applied

Dye sensitized solar cell based on 1,8-naphthalene benzimidazole comprising carboxyl group

S. Erten et al.

EUROPEAN PHYSICAL JOURNAL-APPLIED PHYSICS (2007)

Article Chemistry, Multidisciplinary

Microwave-mediated synthesis of lophine: Developing a mechanism to explain a product

R. David Crouch et al.

JOURNAL OF CHEMICAL EDUCATION (2006)

Article Chemistry, Multidisciplinary

Combined experimental and DFT-TDDFT computational study of photoelectrochemical cell ruthenium sensitizers

MK Nazeeruddin et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)

Review Pharmacology & Pharmacy

Imidazoline antihypertensive drugs: a critical review on their mechanism of action

B Szabo

PHARMACOLOGY & THERAPEUTICS (2002)