4.6 Review

Supercapacitors of Nanocrystalline Covalent Organic Frameworks-A Review

Journal

CRYSTALS
Volume 12, Issue 10, Pages -

Publisher

MDPI
DOI: 10.3390/cryst12101350

Keywords

covalent organic frameworks; supercapacitor; energy storage; electrode materials

Funding

  1. National Natural Science Foundation of China [22005150]
  2. Natural Science Foundation of Jiangsu [BK20200825]
  3. Jiangsu Specially Appointed Professor program
  4. Jiangsu Provincial Scientific Research and Practice Innovation Program [KYCX22_1191]
  5. Startup Foundation for Introducing Talent of NUIST

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Due to their highly changeable porosity and adaptable skeletons, covalent organic frameworks (COFs) have been frequently used in supercapacitors. However, the application of COFs has been limited by the primary organic component preventing electron conduction and the challenge of fully utilizing interior active sites. Therefore, enhancing the conductivity of COFs is a crucial research direction to overcome these limitations.
Due to their highly changeable porosity and adaptable skeletons, covalent organic frameworks (COFs) have been frequently used in supercapacitors. Additionally, COFs are a wonderful match for supercapacitors' requirements for quick carrier migration and ion catalysis. COFs exhibit significant potential and limitless opportunities in electrochemical storage supercapacitors. The applicability of COFs has, nonetheless, been limited because the primary organic component prevents electron conduction and the interior active sites are challenging to fully utilize. The conductivity enhancement of COFs has been the subject of extensive research to solve these challenges. This review begins by outlining the features of COFs in the context of their use in supercapacitors and their methods of synthesis. The application of previously published COF materials in supercapacitors were evaluated including electrode materials and solid-state devices. Finally, essential aspects and potential problems are discussed as the exceptional performance characteristics of COFs are illustrated from a supercapacitor standpoint. This review also forecasts the future of COF-based supercapacitor development.

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