4.7 Review

MXene-Based Porous Monoliths

Journal

NANOMATERIALS
Volume 12, Issue 21, Pages -

Publisher

MDPI
DOI: 10.3390/nano12213792

Keywords

2D nanomaterials; MXenes; porous architecture; assembly

Funding

  1. National Natural Science Foundation of China [51903011, 52173018]
  2. Beijing Natural Science Foundation [2222071]
  3. U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Materials Sciences and Engineering Division [DE-AC02-05-CH11231, KCTR16]

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The development of MXene-based porous monoliths has shown diversity in terms of microstructures, focusing on pore design and how the porous microstructure affects application performance.
In the past decade, a thriving family of 2D nanomaterials, transition-metal carbides/nitrides (MXenes), have garnered tremendous interest due to its intriguing physical/chemical properties, structural features, and versatile functionality. Integrating these 2D nanosheets into 3D monoliths offers an exciting and powerful platform for translating their fundamental advantages into practical applications. Introducing internal pores, such as isotropic pores and aligned channels, within the monoliths can not only address the restacking of MXenes, but also afford a series of novel and, in some cases, unique structural merits to advance the utility of the MXene-based materials. Here, a brief overview of the development of MXene-based porous monoliths, in terms of the types of microstructures, is provided, focusing on the pore design and how the porous microstructure affects the application performance.

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