4.7 Article

Low-Temperature UVO-Sintered ZnO/SnO2 as Robust Cathode Buffer Layer for Ternary Organic Solar Cells

Journal

NANOMATERIALS
Volume 12, Issue 18, Pages -

Publisher

MDPI
DOI: 10.3390/nano12183149

Keywords

ternary organic solar cells; cathode buffer layer; ZnO nanoparticles; SnO2; UVO sintering

Funding

  1. Education Department of Hunan Province [21B0593]
  2. Hunan Provincial Natural Science Foundation of China [2021JJ40227]
  3. Training Program of Innovation and Entrepreneurship for Undergraduates of Hunan Province [3726]
  4. Science and Technology Program of Hunan Province [2019TP1014]

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The bilayer structure of ZnO/SnO2 CBL, prepared by the low-temperature UV-ozone sintering process, exhibits exceptional performance in organic solar cells with a power conversion efficiency of 10.56% and improved stability. This process has great application potential due to its low temperature and excellent transmittance.
The cathode buffer layer (CBL) plays a crucial role in organic solar cells (OSCs), and it has been challenging to obtain high-quality CBL by using simple and reliable processes. In this paper, the bilayer structure consisting of ZnO nanoparticles (NPs) and sol-gel SnO2 was prepared by the low-temperature (<100 degrees C) UV-ozone (UVO) sintering process and used as the robust CBL for ternary OSCs based on PTB7-Th:PCDTBT:PC70BM. The results show that the insertion of SnO2 can effectively fill the cracks and pores on the surface of the ZnO NP film, thereby improving the overall compactness and flatness of the CBL and reducing the defect density inside the CBL. Furthermore, the insertion of SnO2 slightly improves the transmittance of the CBL to photons with wavelengths in the range of 400-600 nm, and also increases the electron mobility of the CBL thus facilitating the extraction and transport of the electrons. Compared to the devices using UVO-ZnO and UVO-SnO2 CBLs, the devices with UVO-ZnO/SnO2 CBL exhibit exceptional performance advantages, the best power conversion efficiency (PCE) reaches 10.56%. More importantly, the stability of the devices with ZnO/SnO2 CBL is significantly improved, the device (PCE) still maintains 60% of the initial value after 30 days in air. The positive results show that the UVO-ZnO/SnO2 is an ideal CBL for OSCs, and due to the low-temperature process, it has great application potential in flexible OSCs.

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