4.7 Article

Smart Modulators Based on Electric Field-Triggering of Surface Plasmon-Polariton for Active Plasmonics

Journal

NANOMATERIALS
Volume 12, Issue 19, Pages -

Publisher

MDPI
DOI: 10.3390/nano12193366

Keywords

smart materials; LIPSS; polymer; nanostructures; thin layers; plasmon excitation; sensor; modification; SERS

Funding

  1. Czech Science Foundation (GACR) [20-01639S]
  2. OP VVV Project NANOTECH ITI II [CZ.02.1.01/0.0/0.0/18_069/0010045]

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Design and properties of a plasmonic modulator tunable by electric field are presented. The modulator comprises a periodic surface pattern created on an elastic polymer surface supported by a piezo-substrate, and the amplitude of the pattern can be controlled by an external electric field for fine-tuning the excitation of surface plasmon-polaritons.
Design and properties of a plasmonic modulator in situ tunable by electric field are presented. Our design comprises the creation of periodic surface pattern on the surface of an elastic polymer supported by a piezo-substrate by excimer laser irradiation and subsequent selective coverage by silver by tilted angle vacuum evaporation. The structure creation was confirmed by AFM and FIB-SEM techniques. An external electric field is used for fine control of the polymer pattern amplitude, which tends to decrease with increasing voltage. As a result, surface plasmon-polariton excitation is quenched, leading to the less pronounced structure of plasmon response. This quenching was checked using UV-Vis spectroscopy and SERS measurements, and confirmed by numerical simulation. All methods prove the proposed functionality of the structures enabling the creation smart plasmonic materials for a very broad range of advanced optical applications.

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