4.5 Article

Processes Associated with Multiphase Dolomitization and Other Related Diagenetic Events in the Jurassic Samana Suk Formation, Himalayan Foreland Basin, NW Pakistan

Journal

MINERALS
Volume 12, Issue 10, Pages -

Publisher

MDPI
DOI: 10.3390/min12101320

Keywords

Samana Suk Formation; dolomitization; stable and radiogenic isotopes; homogenization temperature; shallow marine carbonates; diagenetic processes; depositional environment; carbonate geochemistry; paleoenvironmental reconstruction

Funding

  1. Higher Education Commission of Pakistan through an international research support initiative program (IRSIP) [I-8/HEC/HRD/2018/8979]

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This study conducted a comprehensive investigation into the diagenetic changes, particularly dolomitization patterns in the Jurassic carbonates of Lesser Himalayan fold and thrust belt in NW Pakistan. The results revealed distinct processes of dolomitization leading to the formation of different types of dolomites within the studied area.
Foreland fold and thrust belts always represent a complex diagenetic history of carbonate succession, particularly multiphase dolomitization, due to the multi-sourcing nature of fluids affecting syn-to post-depositional successions. The present work documents a comprehensive study on the diagenetic changes, particularly dolomitization patterns in the Jurassic carbonates (Samana Suk Fm) in the Lesser Himalayan fold and thrust belt, NW Pakistan. To better understand the processes involved, integrated field/petrographic, geochemical, isotopic, and micro-thermometric studies were carried out. Field observations indicate that dolostones appear as light grey to brown stratabound and patchy units within the formation. Petrographic analysis reveals that fabric destructive matrix dolomite (RD-I) and fabric preserving replacive dolomite (RD-II) phases are present as distinct units. In addition, saddle dolomite cement (SD) and fracture-filling calcite (CC) are also observed in association with replacive dolomite cement. Geochemical analysis (EPMA) showed that Fe, Mn, and Ba concentrations in matrix dolomite are relatively less than those of replacive/saddle dolomite and fracture-filling calcite, suggesting a hydrothermal source of replacive/saddle dolomite in reducing conditions. Furthermore, stable isotope studies of RD-I showed non-depleted delta O-18 values, which represent coeval seawater signatures of Jurassic carbonates. RD shows depleted delta O-18 values and non-depleted delta C-13, respectively, indicating burial or elevated temperature of dolomitization. Fracture-filled calcite represents lighter delta O-18 values and delta C-13, indicative of relatively high temperatures. Sr-87/Sr-86 ratios of all diagenetic phases range from 0.707718 to 0.710747, showing more radiogenic values indicates interaction fluids with more radiogenic sources. Fluid inclusion micro-thermometry data of saddle dolomite shows T-H ranging from 102.8 to 186 degrees C, and salinity ranging from 11.7 to 19.4 eq. wt.% NaCl, suggesting hot saline brines are responsible for the dolomitization. Fracture-filling calcite shows T-H ranging from 68.0 to 98.4 degrees C and salinity ranging from 6.9 to 13.1 eq. wt.%. NaCl suggests moderately hot and saline solutions are responsible for their formation. In conclusion, the above-mentioned studies indicate two distinct processes of dolomitization are involved in the formation of matrix and replacive/saddle-type dolomites. RD-I has formed in the evaporative setting, whereas RD has formed due to the interaction of hydrothermal fluids during burial. Fracture-filling calcite is produced from hot subsurface solutions during uplift related to the Himalayan orogeny.

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