4.6 Article

The Conversion of Waste Biomass into Carbon-Supported Iron Catalyst for Syngas to Clean Liquid Fuel Production

Journal

CATALYSTS
Volume 12, Issue 10, Pages -

Publisher

MDPI
DOI: 10.3390/catal12101234

Keywords

biomass; Fischer-Tropsch synthesis; carbon-supported iron catalyst; gasoline; diesel

Funding

  1. King Saud University, Riyadh, Saudi Arabia [RSP2022R448]

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This study investigates the effects of temperature and potassium promoter on the conversion of syngas to liquid fuels using waste biomass-derived activated carbon and carbon-supported iron-based catalysts. The results show that the addition of potassium promoter significantly increases the gasoline and diesel production, and the iron particles are evenly distributed on the surface of activated carbon.
Syngas has been utilized in the production of chemicals and fuels, as well as in the creation of electricity. Feedstock impurities, such as nitrogen, sulfur, chlorine, and ash, in syngas have a negative impact on downstream processes. Fischer-Tropsch synthesis is a process that relies heavily on temperature to increase the production of liquid fuels (FTS). In this study, waste biomass converted into activated carbon and then a carbon-supported iron-based catalyst was prepared. The catalyst at 200 degrees C and 350 degrees C was used to investigate the influence of temperature on the subsequent application of syngas to liquid fuels. Potassium (K) was used as a structural promoter in the Fe-C catalyst to boost catalyst activity and structural stability (Fe-C-K). Low temperatures (200 degrees C) cause 60% and 80% of diesel generation, respectively, without and with potassium promoter. At high temperatures (350 degrees C), the amount of gasoline produced is 36% without potassium promoter, and 72% with promoter. Iron carbon-supported catalysts with potassium promoter increase gasoline conversion from 36.4% (Fe-C) to 72.5% (Fe-C-K), and diesel conversion from 60.8% (Fe-C) to 80.0% (Fe-C-K). As seen by SEM pictures, iron particles with potassium promoter were found to be equally distributed on the surface of activated carbon.

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