Journal
CATALYSTS
Volume 12, Issue 10, Pages -Publisher
MDPI
DOI: 10.3390/catal12101196
Keywords
graphitic carbon nitride; boron and phosphorus co-doped; CO2 cycloaddition; epoxides; Bu4NBr
Categories
Funding
- Civil Aviation Development Fund Education Talents Project [0252101]
- Key Project of Civil Aviation Flight University of China [ZJ2020-06]
- general fund of Civil Aviation Flight University of China [BSJ2021-2, BSJ2021-3, BSJ2022-6]
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This study focuses on the application of boron and phosphorus co-doped graphitic carbon nitride catalyst for the cycloaddition reaction of CO2 and epoxides. Among the catalysts tested, BP-CN-1 showed the best catalytic performance and displayed excellent recyclability.
The development of a cost-effective heterogeneous catalytic system for the cycloaddition reaction of CO2 and epoxides is of great importance. In this manuscript, three kinds of boron and phosphorus co-doping graphitic carbon nitride (BP-CN) were prepared and characterized. Among them, BP-CN-1 displayed the optimal catalytic performance in the presence of Bu4NBr (tetrabutylammonium bromide) for the CO2 cycloaddition with propylene oxide, and 95% propylene carbonate yield was obtained under a 120 degrees C, 2 MPa, 6 h condition. Moreover, the BP-CN-1/Bu4NBr catalytic system is compatible with various epoxides and also exhibits excellent recycling performance under metal- and solvent-free conditions. Hence, BP-CN-1 exhibited an attractive application for the efficient fixation of CO2 due to the simple, eco-friendly synthesis route and effective catalytic activity.
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