4.6 Article

From Biogas to Hydrogen: A Techno-Economic Study on the Production of Turquoise Hydrogen and Solid Carbons

Journal

SUSTAINABILITY
Volume 14, Issue 17, Pages -

Publisher

MDPI
DOI: 10.3390/su141711050

Keywords

biogas; hydrogen; methane; techno-economic; thermocatalytic cracking

Funding

  1. South African Department of Science and Innovation (DSI) [C6GC40]
  2. Council for Scientific and Industrial Research (CSIR) [C1GEN91]
  3. Royal Society [FLR\R1\201528]

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Biogas, a renewable feedstock for hydrogen production, has been studied using a techno-economic approach. The scale and diversification of biogas plants are crucial for the feasibility of biogas-to-hydrogen projects. It has been shown that producing hydrogen at a target price of USD 3/kg or lower is not feasible with current plant sizes. Retrofitting modular units for hydrogen production in self-funded anaerobic digestor plants would only make financial sense at higher biogas production capacities. The cost competitiveness is dependent on the type of carbon formed, with low-grade carbon black negatively impacting economic feasibility. Hydrogen produced from biogas competes with green hydrogen production costs rather than grey hydrogen production.
Biogas is a renewable feedstock that can be used to produce hydrogen through the decomposition of biomethane. However, the economics of the process are not well studied and understood, especially in cases where solid carbons are also produced, and which have a detrimental effect on the performance of the catalysts. The scale, as well as product diversification of a biogas plant to produce hydrogen and other value-added carbons, plays a crucial role in determining the feasibility of biogas-to-hydrogen projects. Through a techno-economic study using the discounted cash flow method, it has been shown that there are no feasible sizes of plants that can produce hydrogen at the target price of USD 3/kg or lower. However, for self-funded anaerobic digestor plants, retrofitting modular units for hydrogen production would only make financial sense at biogas production capacities of more than 412 m(3)/h. A sensitivity analysis has also shown that the cost competitiveness is dependent on the type of carbon formed, and low-grade carbon black has a negative effect on economic feasibility. Hydrogen produced from biogas would thus not be able to compete with grey hydrogen production but rather with current green hydrogen production costs.

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