One-Dimensional Numerical Simulation of Pt-Co Alloy Catalyst Aging for Proton Exchange Membrane Fuel Cells

The service life of catalysts is a key aspect limiting the commercial development of proton exchange membrane fuel cells (PEMFCs). In this paper, a one-dimensional degradation model of a Pt-Co alloy catalyst in the cathode catalytic layer (CCL) of a PEMFC is proposed, which can track the catalyst size evolution in real time and demonstrate the catalyst degradation during operation. The results show that severe dissolution of particles near the CCL/membrane leads to uneven aging of the Pt-Co alloy catalyst along the CCL thickness direction. When the upper potential limit (UPL) is less than 0.95 V, it does not affect the catalyst significantly; however, a slight change may cause great harm to the catalyst performance and service life after UPL > 0.95 V. In addition, it is found that operating temperature increases the Pt mass loss on the carbon support near the CCL/membrane side, while it has little effect on the remaining Pt mass on the carbon support near the CCL/GDL side. These uncovered degradation mechanisms of Pt-Co alloy provide guidance for its application in PEMFCs.

Automated summary

This paper proposes a one-dimensional degradation model for the Pt-Co alloy catalyst in the cathode catalytic layer of a PEMFC, which can track the catalyst size evolution in real time and demonstrate the catalyst degradation during operation. The results show that severe dissolution of particles near the CCL/membrane leads to uneven aging of the Pt-Co alloy catalyst along the CCL thickness direction. Furthermore, it is found that a slight change in the upper potential limit can cause great harm to the catalyst performance and service life after a certain threshold. The study also reveals that operating temperature affects the Pt mass loss on the carbon support near the CCL/membrane side, but has little effect on the remaining Pt mass near the CCL/GDL side.