Journal
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
Volume -, Issue -, Pages -Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.2c04183
Keywords
green materials; vitrimers; conductive foam; electrical properties; lightweight
Categories
Funding
- Ministry of Science and Technology of Taiwan
- [MOST 110-2634-F-027-001]
Ask authors/readers for more resources
In this study, bio-based poly(imine-amide)s (PIAs) were synthesized and demonstrated to have a satisfactory catalyst-free thermally malleable polymer network. These PIAs showed excellent performance in recyclability and foamability, and when combined with multiwalled carbon nanotubes (MWCNTs), exhibited high electrical conductivity and EM-shielding properties. The study presents a green covalent adaptable network for preparing lightweight nanocomposites with desirable properties.
Covalent adaptable networks constructed in biobased cross-linked polymers are used for the thermal-loop process for thermoset materials and composites. In this study, bio-based poly(imine-amide)s (PIAs; biomass content >85%) were synthesized from the lignin-derived monomer vanillin, citrate ester (triethyl citrate), and 1,4-diaminobutane via a condensation reaction. The imide bonds accompanied by a dynamic covalent nature provided PIAs with a satisfactory catalyst-free thermally malleable polymer network. The synthesized PIAs unveil toughness and ductility due to the combined effect of amide and imide structures and become thermally malleable in a few seconds. These PIAs show advanced performance in recyclability (efficient reprocessing) and have excellent foamability (suitable for good sCO2 compatibility and diffusion), as the foams produced via green sCO2 batch foaming technology have an expansion ratio of up to 12.1. PIA/multiwalled carbon nanotube (MWCNT) nanocomposites exhibit high electric conductivity (10-2 to 102 S cm-1 in the range of 1-10 wt % MWCNTs), low percolation threshold (0.43%), and excellent EM-shielding properties (above 70 dB at 10 wt % MWCNTs). More promisingly, the electrical conductivity and EM-shielding properties of these PIA/MWCNT nanocomposites are enhanced by forming microcellular structures. This study presents the molecular structure of a green covalent adaptable network with potential foamability and reprocessing ability, which can be used to prepare lightweight nanocomposites with excellent electrical conductivity and EMI-shielding properties.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available