Journal
INTERNATIONAL JOURNAL OF ENVIRONMENTAL RESEARCH AND PUBLIC HEALTH
Volume 19, Issue 19, Pages -Publisher
MDPI
DOI: 10.3390/ijerph191912879
Keywords
Danube; Serbia; major elements; trace elements; sediments; soils; INAA; felsic material; contamination
Funding
- Joint Serbia-JINR project Monitoring of trace metal elements including lanthanides in the environmental samples as potential pollutants
- Ministry of Education, Science, and Technological Development of Serbia [451-03-68/202214/200017]
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This study analyzed the major elements and trace elements in sediment samples from the Serbian Danube River using INAA. The distribution of major elements was uniform, with little influence from sampling locations. The distribution of trace elements showed similarity to reference samples and the location of the river. The considered contaminating elements exceeded the pollution threshold, indicating significant anthropogenic contamination and raising concerns about the impact on water quality and biota.
To determine the nature and origin of the unconsolidated bottom sediments, as well as to demonstrate and quantify the presence of Presumably Contaminating Elements (PCE) in the Serbian Danube River, as a novelty, the mass fractions on nine major elements as oxides-SiO2, TiO2, Al2O3, FeO, MnO, MgO, CaO, Na2O, and K2O, as well as Sc, V, Cr, Co, Ni, Cu, Zn, As, Rb, Sr, Zr, Sb, Cs, Ba, La, Hf, Ta, W, Th, and U were determined by Instrumental Neutron Activation Analysis (INAA) in 13 sediment samples collected between Belgrade and Iron Gate 2 dam. INAA was chosen for its ability to perform elemental analysis without any preliminary sample treatment that could introduce systematic errors. The distribution of major elements was relatively uniform, with the sampling locations having less influence. Concerning the trace elements, excepting the PCE Cr, Ni, Cu, Zn, As, and Sb, their distributions presented the same remarkable similarity to the Upper Continental Crust (UCC), North American Shale Composite (NASC), Average Bottom Load (ABL), and Average Dobrogea Loess (AVL), and were in good concordance with the location of the Serbian Danube River in the Pannonian Plain. In the case of considered PCE, both Enrichment Factor and Pollution Load Index showed values higher than the pollution threshold, which pointed towards a significant anthropogenic contamination, and rising concern to what extent the water quality and biota could be affected.
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