Journal
JOURNAL OF MATERIALS SCIENCE
Volume 51, Issue 18, Pages 8728-8736Publisher
SPRINGER
DOI: 10.1007/s10853-016-0137-8
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Funding
- Outstanding Youth Scientific Innovation Team of Colleges and Universities in Hubei Province [T201406]
- National Natural Science Foundation of China [51403167, 51374155]
- Science and Technology Support Program of Hubei Province [2014BCB034]
- Scientific Research Foundation of Wuhan Institute of Technology [K201508]
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In the present work, by using the in situ polymerization of aniline in acidic aqueous solution of PVA and freezing-thawing method, the reinforced conducting polymer hydrogel of polyaniline/polyvinyl alcohol (PANI/PVA) was prepared and directly used as the self-supported electrode for supercapacitor. The chemical structure of PANI/PVA hydrogel was characterized by UV-Vis, and the three-dimensional (3D) interconnected hierarchical nanoporous structure was observed by scanning electron microscopy. The measurement of compressive strength demonstrated the high mechanical strength of the hydrogel. The electrochemical properties of PANI/PVA hydrogel electrodes were evaluated by using cyclic voltammetry, electrochemical impedance spectroscopy and galvanostatic charge/discharge, which indicated their good responsiveness and rate capability, low resistance, high specific capacitance (240 F/g at current density of 1 A/g) and excellent cycling stability. The easily fabricated PANI/PVA hydrogel combined hierarchical nanoporous microstructure, self-supported feature and favorable capacitive behavior and provided a new strategy for constructing high-performance electrode for supercapacitors.
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