Journal
JOURNAL OF MATERIALS SCIENCE
Volume 52, Issue 1, Pages 628-642Publisher
SPRINGER
DOI: 10.1007/s10853-016-0360-3
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- IWT-Belgium
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Mg-Zn-Al hydrotalcites and derived mixed oxides with different Mg2+-to-Zn2+ ratios were prepared by co-precipitation in super-saturated conditions, followed by thermal decomposition at 500 A degrees C. The synthesized materials were evaluated as catalysts for the self-condensation of octanal in order to establish structure-to-functionality properties of the prepared materials. The presence of zinc affects the structural and textural properties of the as-synthesized hydrotalcites and derived mixed oxides, and provokes a remarkable modification on the acidic-basic properties of the materials as studied by CO2 and NH3-TPD. The presence of Zn2+ caused an increment in the concentration of surface acidic sites compared to the binary Mg-Al system. The samples characterized by a Zn/Mg ratio aecurrency sign1 showed the optimal ratio of acidic and basic sites and the best catalytic performance for the production of the alpha,beta-unsaturated aldehyde. The reconstruction of the layered materials (starting from the mixed oxides) caused an increment in the concentration of surface OH- groups, further modifying the selectivity of the reaction.
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