4.6 Article

Ultrafine-Grained Tungsten Heavy Alloy Prepared by High-Pressure Spark Plasma Sintering

Journal

MATERIALS
Volume 15, Issue 17, Pages -

Publisher

MDPI
DOI: 10.3390/ma15176168

Keywords

tungsten heavy alloy; ultra-fine grain; high pressure; spark plasma sintering; hardness

Funding

  1. National Key Research and Development Plan of China [2021YFB3701400]
  2. National Natural Science Foundation of China [92163208, 51902233, 51521001, 51832003]
  3. Hubei Key Research and Development Plan [2020BAB063]

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In this study, highly dense and ultrafine-grained tungsten alloy was successfully fabricated at a low temperature and high pressure using spark plasma sintering method.
Tungsten heavy alloy (WHA) is an ideal material employed for kinetic energy penetrators due to its high density and excellent mechanical properties. However, it is difficult to obtain ultrafine-grained tungsten alloy with excellent properties by traditional powder metallurgy method because of severe grain growth at a high sintering temperature with a long soaking time. In this study, the sintering behavior of tungsten alloys was studied at 800 to 1300 degrees C, and highly dense 93W-5.6Ni-1.4Fe (wt.%) WHA was successfully fabricated at a low temperature of 950 degrees C with a high pressure of 150 MPa by spark plasma sintering. The as-sintered tungsten alloy possesses a high relative density (98.6%), ultrafine grain size (271 nm) and high dislocation density (2.6 x 10(16) m(-2)), which results in excellent properties such as a high hardness (1079 HV1). The high sintering pressure is considered to support an additional driving force for the sintering and lead to a low-temperature densification, which effectively limits grain growth.

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