4.6 Review

Photonic Nano-/Microstructured Diatom Based Biosilica in Metal Modification and Removal-A Review

Journal

MATERIALS
Volume 15, Issue 19, Pages -

Publisher

MDPI
DOI: 10.3390/ma15196597

Keywords

diatom; frustules; silica-metal conjugate; absorption; adsorption

Funding

  1. project Advanced biocomposites for tomorrow's economy BIOG-NET - Foundation for Polish Science from the European Regional Development Fund within the Intelligent Development Operational Program 2014-2020 [POIR.04.04.00-00-1792/18-00]

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The siliceous exoskeletal shells of diatoms, known as frustules, have attracted attention for their photoluminescence property and high volume to surface area ratio. They can enhance the plasmonic sensitivity of metal nanoparticles and have excellent adsorption and absorption capabilities, which have been utilized in wastewater treatment. By conjugating noble metals with diatom frustules, the metals become more stable and effective.
The siliceous exoskeletal shells of diatoms, commonly known as frustules, have drawn attention because of their photoluminescence property and high volume to surface area. Photonic biosilica can also enhance the plasmonic sensitivity of nanoparticles. Because of this, researchers have studied the effectiveness of various metal particles after combining with biosilica. Additionally, naturally occurring diatom-based biosilica has excellent adsorption and absorption capabilities, which have already been exploited for wastewater treatment. Moreover, the nanoporous, ultra-hydrophilic frustules can easily accumulate more molecules on their surfaces. As a consequence, it becomes easier to conjugate noble metals with silica, making them more stable and effective. The main focus of this review is to agglomerate the utility of biocompatible diatom frustules, which is a no-cost natural resource of biosilica, in metal modification and removal.

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