4.8 Article

Carbon Nitride Photoredox Catalysis Enables the Generation of the Dioxolanyl Radical for Conjugate Addition Reactions

Journal

ACS CATALYSIS
Volume -, Issue -, Pages -

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acscatal.2c03229

Keywords

carbon nitride; sustainable chemistry; heterogeneous photocatalysis; visible light photocatalysis; conjugate addition; C1 building blocks

Funding

  1. Swiss National Science Foundation
  2. Stipendienfonds Schweizerische Chemi-sche Industrie (SSCI)
  3. ETH Zu rich

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Graphitic carbon nitride (g-C3N4) is a photocatalyst used in the Giese reaction, showing excellent reusability and stability over five cycles with no changes in composition or morphology.
Graphitic carbon nitride (g-C3N4) is used as photocatalyst in the Giese reaction of dioxolane and a wide variety of electron-deficient olefins. The catalyst is shown to be reusable over five cycles with no changes in catalyst composition, morphology, and characteristics observed by scanning electron microscopy, elemental analysis, infrared spectroscopy, and powder X-ray diffraction.

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