4.8 Review

Well-Defined Pdn Clusters for Cross-Coupling and Hydrogenation Catalysis: New Opportunities for Catalyst Design

Journal

ACS CATALYSIS
Volume 12, Issue 19, Pages 11615-11638

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acscatal.2c03345

Keywords

palladium clusters; catalysis; cross-coupling; hydrogenation; catalyst speciation

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Recent studies have shown that the privileged reactivity of higher-order metal clusters can be utilized in widely applied catalytic processes. Small Pdn clusters with unique reactivity, selectivity, and catalyst behavior have been discovered, presenting potential in catalyst design and application. This review focuses on the catalytic applications of Pdn clusters and discusses the underlying structure linked to their reactivity. It further proposes a hypothesis regarding the formation of higher-order Pd species through ligated Pdn clusters.
In recent studies it has been demonstrated that the privileged reactivity of higher-order metal clusters can be exploited in widely applied catalytic processes, particularly cross-coupling reactions and hydrogenative transformations. Relatively small, well-defined Pdn clusters have been known since the 1960s. Unique reactivity, reaction (product) selectivity, and catalyst behavior have been recently uncovered, from which there is much potential in catalyst design and application. Ligated Pdn clusters of a smaller size (where n is less than 6) may form upon degradation of mononuclear Pd species en route to larger particulate Pd (from <5 nm particles to large moribund forms in the >1 mu m range). This review presents the catalytic applications of Pdn clusters. We pay particular attention to the underlying structure of the Pdn clusters, linked to their reactivity. A hypothesis that ligated Pdn clusters may constitute a mechanism by which higher-order Pd species may form (as a bridging point for monoligated Pd species through to PdNPs) is further discussed. Where appropriate, we mention other catalytic reaction processes that complement the discussion focused on cross-coupling and hydrogenation processes.

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