4.5 Article

Polyethylene Glycol (PEG) Non-Ionic Surfactant-Based Reverse Micellar Dyeing of Cotton Fabric with Hot Type Trichloropyrimidine (TCP)-Based Reactive Dyes

Journal

JOURNAL OF NATURAL FIBERS
Volume 20, Issue 1, Pages -

Publisher

TAYLOR & FRANCIS INC
DOI: 10.1080/15440478.2022.2131689

Keywords

Cotton fabric; reactive dyes; hot type; reverse micelle; Non-aqueous dyeing; polyethylene glycol

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This study aimed to examine the feasibility of using a poly(ethylene glycol) (PEG)-based reverse micellar dyeing system for dyeing cotton fabric with hot type trichloropyrimidine (TCP)-based reactive dyes and evaluate the energy-saving potential. The experimental results showed that dyeing fabrics in the reverse micellar system at 90 degrees Celsius achieved higher color yield compared to the conventional water-based system at the same temperature. Further experiments showed that using the reverse micellar system for dyeing cotton at 80 degrees Celsius provided comparable color yield to the conventional water-based system. The reverse micellar dyeing system caused no significant damage to cotton fibers and allowed for the recycling of octane.
This work aims to examine the feasibility of using poly(ethylene glycol) (PEG)-based reverse micellar dyeing system for dyeing cotton fabric with the use of hot type trichloropyrimidine (TCP)-based reactive dyes and to evaluate the possibility of saving the dyeing energy used during the dyeing process. Experimental results show that fabrics dyed in reverse micellar system at 90 degrees C can achieve higher color yield than the conventional water-based system at the same temperature. Further experiments using reverse micellar system for dyeing cotton at 80 degrees C (a reduction of working temperature of 10 degrees C) provided color yield comparable to that of conventional water-based system except the use of yellow dye. Both water-dyed and octane-dyed samples had good to excellent levelness, washing and rubbing fastness and 98.5% of octane could be recycled after distillation. Reflectance curves were identical in shape and the SEM images showed neither of the dyeing systems caused any significant damage to cotton fibers. These findings validated the possibility of using reverse micellar dyeing system for hot type TCP-based reactive dyeing of cotton fabrics at lower coloration temperature and energy consumption.

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