Conductive Screen Printing Inks by Gelation of Graphene Dispersions

This paper describes the gelation of highly concentrated graphene/polymer dispersions triggered by mild heating. The gel formation is only dependent on the concentration of graphene with 3.25 mg mL(-1) as the minimum value for graphene network formation. The graphene gel is then utilized for the preparation of colloidally stable and highly concentrated (52 mg mL(-1)) graphene pastes that demonstrate excellent performance in screen printing down to lines of 40 m in width. Printed patterns dried at 100 degrees C for only 5 min exhibit sheet resistances of 30 ?(-1) at 25 m thickness, thus, removing the need for long-time high temperature annealing, doping, or other treatments. Such a low drying temperature, high printing definition, and compatibility with industrially relevant plastic and paper substrates brings high-volume roll-to-roll application in printed flexible electronics within reach.