4.7 Article

High-temperature corrosion behavior of austenitic stainless steel in quaternary nitrate molten salt nanofluids for concentrated solar power

Journal

SOLAR ENERGY MATERIALS AND SOLAR CELLS
Volume 245, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.solmat.2022.111851

Keywords

Nanofluids; Weight loss method; Quaternary nitrate salt; Stainless steel

Funding

  1. National Natural Science Foundation of China [52076006]
  2. Inner Mongolia Science and Technology Major Project [2021ZD0036]

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Molten salt nanofluids have excellent thermal properties and heat transfer performance, making them a hot research topic. However, there is limited research on the effect of nanofluids on the corrosion of metal materials. This study analyzed the corrosion behavior of stainless steel in molten salt nanofluids using a low melting point quaternary nitrate as the base salt. The addition of SiO2 nanoparticles reduced the corrosion rate of stainless steel, indicating that molten salt nanofluids have good compatibility with metal materials.
Molten salt nanofluids have become a hot research topic due to its excellent thermal properties and heat transfer performance. However, there is a few research on the effect of nanofluids on the corrosion of metal materials. In order to know the influence of molten salt nanofluids on the corrosion of stainless steel, a low melting point quaternary nitrate was used as the base salt to analyze the corrosion law of nanofluids. By means of weight loss method, two different stainless steels (304, 316L) were put into the molten salt nanofluids with SiO2 nano-particles content of 1 wt% to test the corrosion behavior of stainless steel. The results of 500 h corrosion test revealed that the corrosion rate of mixed molten salt on 304 and 316L stainless steel is reduced by the addition of SiO2 nanoparticles. The corrosion rates of molten salt nanofluids on 304 and 316L stainless steel were 0.0433 mm/y and 0.0233 mm/y, respectively. The surface morphology analysis by SEM, EDS, XRD and XPS test showed that the reticular silica nanostructures corrosion layer was formed on the surface of stainless steel, such structure can inhibit the corrosion of stainless steel. Therefore, molten salt nanofluids have the good compatibility with metal materials, and adding nanoparticles in molten salt can reduce the corrosion on stainless steel.

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