Highly Efficient and Selective Visible-Light Driven Photoreduction of CO2 to CO by Metal-Organic Frameworks-Derived Ni-Co-O Porous Microrods

Photocatalytic CO2 reduction by solar energy into carbonaceous feedstock chemicals is recognized as one of the effective ways to mitigate both the energy crisis and greenhouse effect, which fundamentally relies on the development of advanced photocatalysts. Here, the exploration of porous microrod photocatalysts based on novel Ni-Co-O solid solutions derived from bimetallic metal-organic frameworks (MOFs) is reported. They exhibit overall enhanced photocatalytic performance with both high activity and remarkable selectivity for reducing CO2 into CO under visible-light irradiation, which are superior to most related photocatalysts reported. Accordingly, the Ni-0.2-Co-0.8-O microrod (MR-N0.2C0.8O) photocatalyst delivers high efficiency for photocatalytic CO2 reduction into CO at a rate up to approximate to 277 mu mol g(-1) h(-1), which is approximate to 35 times to that of its NiO counterpart. Furthermore, they display a high selectivity of approximate to 85.12%, which is not only better than that of synthesized Co3O4 (61.25%) but also superior to that of reported Co3O4-based photocatalysts. It is confirmed that the Co and Ni species are responsible for CO2-CO conversion activity and selectivity, respectively. In addition, it is verified, by adjusting the Ni contents, that the band structure of Ni-Co-O microrods can be tailored with favorable reduction band potentials, which thus enhance the selectivity toward CO2 photoreduction.

Automated summary

This paper reports the development of porous microrod photocatalysts based on Ni-Co-O solid solutions derived from metal-organic frameworks. They exhibit high activity and selectivity in reducing CO2 to CO under visible-light irradiation. The band structure of the photocatalysts can be tailored by adjusting the Ni content, leading to enhanced selectivity for CO2 photoreduction.