Intergranular precipitation and chemical fluctuations in an additively manufactured 2205 duplex stainless steel

Fluctuations in energy distribution during additive manufacturing (AM) can result in spatial and temporal thermal transients. These transients can lead to complexities, most significantly when alloys with multi phases are subjected to AM. Here we unveil such complexities in a duplex stainless steel, where we report an unanticipated formation of a Ni-Mn-Si rich phase at grain boundaries and a local fluctuation in Cr and Fe concentrations in regions close to grain boundaries, providing Cr-rich precursors for Cr2N formation after laser powder bed fusion (LPBF). The formation of these phases is believed to be due to severe thermal gyrations and thermal stresses associated with LPBF resulting in a high-volume fraction of ferrite supersaturated with N and Ni, and a high density of dislocations accelerating diffusion and phase transformations.

Automated summary

Fluctuations in energy distribution during additive manufacturing can result in thermal transients, particularly in alloys. In this study, the complexities in a duplex stainless steel during laser powder bed fusion were investigated. The formation of Ni-Mn-Si rich phase at grain boundaries and local fluctuation in Cr and Fe concentrations were observed, providing precursors for Cr2N formation. These phases were attributed to severe thermal gyrations and thermal stresses associated with laser powder bed fusion.