4.7 Article

Secondary-field boosted caloric effect associated with first-order phase transition, a quasi-direct measurement

Journal

SCRIPTA MATERIALIA
Volume 218, Issue -, Pages -

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.scriptamat.2022.114836

Keywords

Quasi-direct method; Caloric effect; First-order phase transition; Hysteresis; Reversible isothermal entropy change

Funding

  1. National Natural Science Foundation of China [U1932127]
  2. Key Research Program of Frontier Sciences, Chinese Academy of Sciences (CAS) [QYZDB-SSW-SLH015]

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The researchers proposed a method to measure the caloric effect under the combination of magnetic field and hydrostatic pressure, and successfully enhanced the reversible caloric effect of an alloy material. This method can be applied to study the multicaloric effect in other multiferroic materials and promote the development of solid-state refrigeration in practical applications.
Caloric cooling originating from solid-state phase transition triggered by external fields is identified to be a green and efficient alternative to the traditional refrigeration technology based on vapor expression. If multi degrees of freedoms are coupled at the phase transition, the caloric effect can be stimulated by multi stimuli. However, characterizing the caloric effect under multi fields is still challenging. Here, we proposed a quasi-direct method for caloric effect measurements under the combination of magnetic field and hydrostatic pressure. By combining two external fields in a proper sequence, the reversible caloric effect of Mn0.6Fe0.4NiSi0.5Ge0.5 alloy was markedly enhanced. Our method can be expanded to study the multicaloric effect in other multiferroic materials and promote the development of solid-state refrigeration in practical applications.

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