4.7 Article

Directionally solidified high-entropy (Y0.2Gd0.2Ho0.2Er0.2Yb0.2)3Al5O12/Al2O3 eutectic with outstanding crystallographic texture formation capability

Journal

SCRIPTA MATERIALIA
Volume 220, Issue -, Pages -

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.scriptamat.2022.114939

Keywords

Eutectic ceramic; High entropy ceramic; Directional solidification; Crystallographic texture

Funding

  1. National Natural Science Foundation of China [XLYC2002018]
  2. Natural Science Foundation of Liaoning Province
  3. Liaon-ing Revitalization Talents Program
  4. [2020 -MS -006]
  5. [52130204, U21A2063]

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This study reports a high-entropy DSE ceramic with outstanding crystallographic texture formation capability. Compared to DSE ceramics containing single rare earth elements, the high-entropy DSE ceramic can obtain single crystal phases within a shorter growth distance, which is significant for microstructure control in DSE processing and the uniformity of mechanical properties throughout the material.
Crystallographic texture control is the critical challenge for directionally solidified eutectic (DSE) ceramics. We herein report a high-entropy (Y0.2Gd0.2Ho0.2Er0.2Yb0.2)3Al5O12/Al2O3 DSE ceramic that shows outstanding crystallographic texture formation capability. Based on comprehensive observations of phase composition and eutectic microstructure characteristics, the single crystal phases of high-entropy (5RE0.2)3Al5O12 (RE = rare earth) and Al2O3 are obtained within a much-shortened growth distance (within 15 mm) than those of the single rare earth containing RE3Al5O12/Al2O3 counterparts (typically >= 80 mm). The rapid formation of stable crys-tallographic texture is significant for microstructure control in DSE processing and uniformity of mechanical property along the whole material.

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