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Advanced Mueller matrix ellipsometry: Instrumentation and emerging applications

Journal

SCIENCE CHINA-TECHNOLOGICAL SCIENCES
Volume 65, Issue 9, Pages 2007-2030

Publisher

SCIENCE PRESS
DOI: 10.1007/s11431-022-2090-4

Keywords

ellipsometry; Mueller matrix; Mueller matrix ellipsometry; imaging ellipsometry; high-speed ellipsometry

Funding

  1. National Natural Science Foundation of China [51727809, 52022034, 62175075, 52130504]
  2. Key Research and Development Plan of Hubei Province [2020BAA008, 2021BAA013]

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The paper reviews the principles, system layouts, and data analysis procedures of Mueller matrix ellipsometry (MME). It also introduces various applications of MME in the characterization of surfaces, interfaces, thin films, and nanostructures. The paper further presents new developments in MME, including broadband MME, high-resolution imaging MME, and high-speed MME, as well as emerging applications of MME. Conclusions and perspectives of advanced ellipsometry are drawn and discussed.
Mueller matrix ellipsometry (MME) provides the 4x4 Mueller matrix of a sample under test, which determines how the state of polarization is changed as light interacts with the sample. Due to the redundant information contained in the Mueller matrix, MME has gained more and more extensive applications in the characterization of surfaces, interfaces, thin films, and nanostructures. In addition, the instrumentation of MME has also achieved great developments since its advent in the 1970s. In this paper, we will first review the basic principle as well as the common system layouts of MME for the full Mueller matrix measurement. Then, the basic procedure of ellipsometry data analysis is reviewed. After that, some new developments in MME in our lab for different applications are introduced, including the broadband MME, the high-resolution imaging MME, and the high-speed MME. Some emerging applications of the developed MMEs are also presented. Conclusions and perspectives of the advanced ellipsometry are finally drawn and discussed.

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