Journal
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
Volume 67, Issue 11, Pages 1769-1775Publisher
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0036023622600915
Keywords
uranyl; iodoacetates; crystal structure; Voronoi-Dirichlet polyhedra
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Funding
- Ministry of Education and Science of the Russian Federation
- [075-00697-22-00]
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The crystals of two complexes were synthesized and studied by various methods. The non-covalent interactions in one of the crystals were analyzed and it was found that the nature of the iodine-containing carboxylate ions does not affect the geometric characteristics.
Thecrystals of (CN3H6)(3)[UO2(mia)(3)](2)(NO3) (I) and (CN3H6)(3)[UO2 (mia)(3)](2) (OH) (II), where mia is the monoiodoacetate ion CH2ICOO-, were synthesized and studied by IR spectroscopy, thermogravimetric analysis, and X-ray diffraction. The uranyl-containing [UO2(mia)(3)](-) complexes in the structures of I and II are described by the crystal chemical formula A(B-01)(3), where A = UO22+, B-01 = mia. The non-covalent interactions in the crystals of I were analyzed by the method of molecular Voronoi-Dirichlet polyhedra. Considering the available published data, it was found that the nature of the iodine-containing carboxylate ions (aliphatic or aromatic) does not affect the geometric characteristics (d(I center dot center dot center dot O) and
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