Journal
JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS
Volume 55, Issue 5, Pages 457-470Publisher
TAYLOR & FRANCIS INC
DOI: 10.1080/00222348.2016.1168559
Keywords
blue-light emitter; Chiral; N-(9-fluorenylmet-hoxycarbonyl)-L-alanine; Solubility
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Funding
- Shandong Provincial Natural Science Foundation, China [ZR2012BL11]
- Shandong Provincial Science and Technology Development Plan Project, China [2013GGX10705]
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Poly[N-(9-fluorenylmethoxycarbonyl)-L-alanine] (PN9FA) films with good fluorescence properties and chirality were prepared electrochemically by direct anodic oxidation of N-(9-fluorenylmethoxycarbonyl)-L-alanine (N9FA) in boron trifluoride diethyletherate (BFEE). Results of FT-IR spectral measurements indicated that N9FA was probably polymerized through the coupling at the C (2) and C (7) positions. Results of electrochemical measurements of PN9FA showed good redox activity and stability. The fluorescence spectra indicated that PN9FA films were blue-light emitters. In addition, the structures and properties of the monomer and the polymers were characterized and evaluated with cyclic voltammograms (CVs), 1H-NMR, UV-vis spectra (UV), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM).
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