Hydroclimate reconstruction through MIS 3 in the Middle Paleolithic site of Crvena Stijena (Montenegro) based on hydrogen-isotopic composition of sedimentary n-alkanes

This study presents a hydroclimatic reconstruction from Crvena Stijena (Montenegro, Balkan Peninsula), a rock shelter that has yielded evidence for Middle Paleolithic human occupation. The integration of lipid biomarkers, hydrogen (dD) isotopic compositions of n-alkanes, and organic elemental geochemistry in the 7-m deep vertical sedimentary sequence enables reconstruction of the main hydrological and environmental changes during the MIS 3 and their correlation with the presence at the site. We apply agglomerative hierarchical clustering and principal component analysis to the geochemical, molecular, and stable isotopic data to obtain a robust hydrological record. We find evidence of three aridity trends from the studied period, one of them correlated with the Heinrich Event 5, and humid and cold -temperate conditions in archaeology-rich layers. Our dataset also contributes to the knowledge of past hydrological variability in the Balkan Peninsula, a sensitive area to short-lived climatic shifts, and overall, in the Mediterranean region during the last glacial/interglacial cycle.(c) 2022 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

Automated summary

This study presents a hydroclimatic reconstruction from Crvena Stijena rock shelter in Montenegro, Balkan Peninsula. The researchers integrated lipid biomarkers, hydrogen isotopic compositions, and organic elemental geochemistry to reconstruct the hydrological and environmental changes during the MIS 3. The study found evidence of aridity trends and identified correlations with the Heinrich Event 5.